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5. Give the structural formula of the compounds/reagents A to G.
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- I have this task in organic chemistry (book: Brown's introduction to organic chemisty, global edition). Task 10:42. In (a) I have to tell what the funcion of K2CO3 is in step 1. Is it that CO32- take the hydrogen atom in 1-napthol? Will it then be a SN2 mechanism? In (b) I have to name the amine used in step 2 to form Propanolol. But I can't really find out how to come up with an amine that will make that reaction. Here are two pictures of the task:KMnO4, warm, conc'd reacts with hept-1-ene to yield __________. CO2, hex-1-ene CO2, hexanoic acid Formic acid, pentanoic acid Ethanoic acid, pentanal Formic acid, hexanoneProvide the E2 mechanism for β-elimination reactionemploying 2-chloro-2-methylbutane to prepare 2-methyl-2-butene and 2-methyl-1-butene reaction. Use the actual structures of thereactants and products. Explain which of the alkenes is the major product ofthis reaction ?
- Draw the organic products formed when cyclopentene is treated with each reagent. With some reagents, no reactionoccurs.a. H2 + Pd-Cb. H2 + Lindlar catalystc. Na, NH3d. CH3CO3He. [1] CH3CO3H; [2] H2O, HO–f. [1] OsO4 + NMO; [2] NaHSO3, H2Og. KMnO4, H2O, HO–h. [1] LiAlH4; [2] H2Oi. [1] O3; [2] CH3SCH3j. (CH3)3COOH, Ti[OCH(CH3)2]4, (–)-DETk. mCPBAl. Product in (k); then [1] LiAlH4; [2] H2O1. i.What are the various ways by which alkenes may be synthesized? ii. Give two examples each of Unsymmetrical alkenes and reagents. iii. Give two examples of reactions of alkenes that result in Anti-Markonikov’s addition productsPlease solve correctly: Optio for Q1. a.)2-hexyne b.)3-methyl-1-pentyne c.)3-hexyne d.)1-hexyne e.)4-methy-1-pentyne Q2) a.)Alkenes react with nucleophiles and bases. b.)Alkenes react with electrophiles. c.)In the reactions of alkenes, the p bond is not always broken. d.)Alkenes contain double bonds from two sp-hybridized carbon atoms.
- Alcohols are important for organic synthesis, especially in situations involving alkenes. The alcohol might be the desired product, or the OH group might be transformed into another functional group via halogenation, oxidation, or perhaps conversion to a sulfonic ester derivative. Formation of an alcohol from an alkene is particularly powerful because conditions can be chosen to produce either the Markovnikov or non-Markovnikov product from an unsymmetrical alkene. Using your reaction roadmap as a guide, show how to convert 4-methyl-1-pentene into 5-methylhexanenitrile. You must use 4-methyl-1-pentene and sodium cyanide as the source of all carbon atoms in the target molecule. Show all reagents needed and all molecules synthesized along the way.What are ALL of the products of buta-1,3-diene and bromine water? I know how to get to the major product (bromine and OH both to the left of the double bond) but don't know how to get to the minor product (bromine to the left, OH to the right)?Use the Hammond postulate to explain why (CH3)2C = CH2 reacts faster than CH3CH = CH2 in electrophilic addition of HX.
- Tunicates are marine animals that are called "sea squirts" because when they are taken out of water, they tend to contract and expel seawater. Lepadiformine is a cytotoxic agent (toxic to cells) isolated from a marine tunicate. During a recent synthesis of lepadiformine, the investigators observed the formation of an interesting by-product (3) while treating diol 1 with a reagent similar in function to PBr3 (J. Org. Chem. 2012, 77, 3390–3400):A hydrocarbon of unknown structure has the formula C8H10. On catalytichydrogenation over the Lindlar catalyst, 1 equivalent of H2 is absorbed. Onhydrogenation over a palladium catalyst, 3 equivalents of H2 are absorbed.(a) How rnany degrees of unsaturation are present in the unknown?(b) How many triple bonds are present?(c) How many double bonds are present?(d) How many rings ar e present?(e) Draw a structure that fits the data.help me please Please fill in the reagents,intermediates, and/or products of the following reactions. all the reactions shall be covered in Chapter 12-15 from Organic Chemistry, 6th Edition by Marc Loudon and Jim Parise.