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Q: [H*]?
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Q: E1O OEt H H. A H NaOEt, E1OH NaOEt, E1OH H В EtO OEt C NaOEt, ELOH
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- 10.a) In the box at the left, indicate whether the reaction takes place through an SN2, SN1, E2, or E1 mechanism. b) Draw the mechanism and predict the product, including stereochemistrySynthesis 2,3,4,5,6,7 − Hexahydro − 1H − Indene is categorized as an unsaturated bisiclo compound, following its structure: a) Draw the reaction mechanism aboveb) Draw the structure 2,3,4,5,6,7 − Hexahydro − 1H − Indenec) Suggest the preferred solvent in the above reaction and whyThe iodination of acetovanillone (1-(4-hydroxy-3-methoxyphenyl)ethan-1-one) occurs in the following reaction: C9H10O3 + NaI + NaOCl --> C9H10O3I + NaCl Draw the complete reaction mechanism of acetovanillone including curved arrows.
- 1. For the following reaction step, indicate which pattern of arrow pushing it represents. a. proton transferb. rearrangementc. loss of a leaving group2. Melphalan, a drug used in chemotherapy, reacts with itself in the body before binding with its target, as illustrated in the mechanism below. What is the first pattern of arrow pushing seen in this reaction? a. rearrangementb. loss of a leaving groupc. nucleophilic attackDraw the mechanism ffrom benzaldehyde to this using: i)NaBH4 ii)TsCl, py iii)NaCN iiii)H+, H2OA. Draw the two products of the reaction below: B. Identify the major product of the reaction and draw the mechanism leading to the formation of that product.
- a.) Draw curved arrows for each step of following mechanism. B.) predict outcome of following 4 reactions. If the reaction does not occur write N.R. into box and explain why.Draw the reactant RCHDBr with S absolute configuration, the draw the product of R’OH + RCHDBr (with S-configuration) through an SN2 reactions.a) Draw the mechanism, using good curved arrow notation, for the reaction of 2-methyl-2- butene with bromine in water, omitting any stereochemistry: b) (R)-3-butyn-2-ol is treated with 2 mol of HBr, yielding optically active Compound A (C4H8OBr2). Draw the structure of the reaction with the correct stereochemistry. c) Name Compound A above, including stereochemistry. d) Compound A is treated with HBr to yield Compound B (C4H7Br3). The resulting solution is optically inactive. Draw the product(s) obtained and explain why there is a loss in optical activity.
- a. Which of the following would be more reactive in an electrophilic substitution and why? Use 1image b. Arrange the compounds in each set-in order of decreasing reactivity (fastest and slowest) toward electrophilic aromatic substitution and explain. Use 2 imageIn an E1 mechanism the leaving group leaves first to form a carbocation andsubsequently a proton is removed by a base to form the alkene. In an E2 mechanism theproton and the leaving group leave at the same time. The compound shown belowundergoes an Elimination reaction in a two-step mechanism that does not follow the orderor steps as described above (not E1 or E2) a. Draw the mechanism and give the product of the elimination reaction.b. Why do you think this reaction follows this unusual elimination reaction? Support youranswer with all relevant structure(s)A8 Is there anyone who can provide this pericyclic rxn mechanism?