How could you prepare the following amides using an acid chloride and an amine or ammonia? (a) CH CH₂CONHCH3 (b) N,N-Diethylbenzamide (c) Propanamide
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- Show how you would use appropriate acyl chlorides and amines to synthesize thefollowing amides.(a) N,N-dimethylacetamide (b) acetanilide (PhNHCOCH3)Show how you would use appropriate acyl chlorides and amines to synthesize thefollowing amides.(a) N,N-dimethylacetamide (b) acetanilide (PhNHCOCH3)(c) cyclohexanecarboxamide (d)What acyl chloride and amine are required to synthesize the following amides?a. N-ethylbutanamide b. N,N-dimethylbenzamide
- Show how to synthesize the following amines from the indicated starting materials byreductive amination. (±)-amphetamine 1-phenylpropan-2-oneWhen a amide is treated with SOCl2 ? What arises ?What carboxylic acid and amine are needed to synthesize the pain reliever phenacetin? Phenacetin was once a component of the over-the-counter pain reliever APC (aspirin, phenacetin, caffeine), but it is no longer used because of its kidney toxicity.
- Indicate whether the following statement is true or false. Aliphatic amines are more basic than ammonia, whereas aromatic amines are less basic than ammonia. When amines are reacted with bases, they form ammonium salts. Benzenesulfonyl chloride or p-toluenesulfonylchloride give N-substituted sulfonamides with primary and secondary amines. Derivative of primary amines is insoluble in dilute NaOHShow how to synthesize the following amines from the indicated starting materials.(a) N-cyclopentylaniline from aniline (b) N-ethylpyrrolidine from pyrrolidineGive the products expected when the following tertiary amines are treated with a peroxyacid and heated.(a) N,N-dimethylhexan-2-amine
- Be sure to answer all parts. Be sure to include the ion charges. What products are formed when the following amine is treated with HCl: (CH3CH2)2NH arrow draw structure ... + Cl− Be sure to answer all parts. What ammonium salt is formed when the amine is treated with HCl.Draw a structural formula for each amine and amine derivative. (a) N,N-Dimethylaniline (b) Triethylamine (c) tert-Butylamine (d) 1,4-Benzenediamine (e) 4-Aminobutanoic acid (f) (R)-2-Butanamine (g) Benzylamine (h) trans-2-Aminocyclohexanol (i) 1-Phenyl-2-propanamine (amphetamine) (j) Lithium diisopropylamide (LDA) (k) Benzyltrimethylammonium hydroxide (Triton B)The hydrolysis of an amide in acidic conditions forms A. a carboxylate salt and an alcohol B. a carboxylate salt and an amine C. an alcohol and an amine salt (an ammonium ion) D. a carboxylic acid and an amine salt (an ammonium ion)