How did you get this? k===0.693t1/20.69315 hrs0.0462 hrs−1k=0.693t1/2=0.69315 hrs=0.0462 hrs   0.693 a 102.0 nanogram(ng) sample of sodium-24 was stored in a lead-lined cabinet for 2.5 days How much sodium-24 remained? The half-life os sodium -24 is 15 hours    _________ ng sodium -24 remain  check_circle Expert Answer thumb_up   thumb_down Step 1 Radioactive decay is a first order reaction. Conversion of days into hours: 1 day2.5 days===24 hrs2.5×2460 hrs1 day=24 hrs2.5 days=2.5×24=60 hrs Calculation of k: k===0.693t1/20.69315 hrs0.0462 hrs−1k=0.693t1/2=0.69315 hrs=0.0462 hrs-1 Step 2 Radioactive decay is a first order reaction, therefore: [A]=[Ao] e−kt[A]=[Ao] e-kt where [A] is the final amount remained at time t, [Ao] is the initial amount. Putting values: [A]====102.0 ng×e−0.0462 hrs−1×60 hrs102.0 ng×e−2.772102.0 ng×0.062546.38 ng[A]=102.0 ng×e-0.0462 hrs-1×60 hrs=102.0 ng×e-2.772=102.0 ng×0.06254=6.38 ng Thus 6.38 ng of sodium-24 remained.

Chemistry for Engineering Students
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ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.72PAE
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How did you get this?

k===0.693t1/20.69315 hrs0.0462 hrs−1k=0.693t1/2=0.69315 hrs=0.0462 hrs

 

0.693

a 102.0 nanogram(ng) sample of sodium-24 was stored in a lead-lined cabinet for 2.5 days How much sodium-24 remained? The half-life os sodium -24 is 15 hours 

 

_________ ng sodium -24 remain 

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Expert Answer

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Step 1

Radioactive decay is a first order reaction.

Conversion of days into hours:

1 day2.5 days===24 hrs2.5×2460 hrs1 day=24 hrs2.5 days=2.5×24=60 hrs

Calculation of k:

k===0.693t1/20.69315 hrs0.0462 hrs−1k=0.693t1/2=0.69315 hrs=0.0462 hrs-1

Step 2

Radioactive decay is a first order reaction, therefore:

[A]=[Ao] e−kt[A]=[Ao] e-kt

where [A] is the final amount remained at time t, [Ao] is the initial amount.

Putting values:

[A]====102.0 ng×e−0.0462 hrs−1×60 hrs102.0 ng×e−2.772102.0 ng×0.062546.38 ng[A]=102.0 ng×e-0.0462 hrs-1×60 hrs=102.0 ng×e-2.772=102.0 ng×0.06254=6.38 ng

Thus 6.38 ng of sodium-24 remained.

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