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- A pellet of benzoic acid standard was combusted in a bomb calorimeter to determine the experimental calorimeter constant. After 6 mins of monitoring the temperature, the bomb was fired. The following data were obtained. mole of benzoic acid: 0.0049 mol mass of burnt fuse wire: 0.0125 g qwire,surr: 5858 J/g ΔHcombustion of benzoic acid: -3228.0 kJ/mol Δng (combustion of benzoic acid): -0.5 mol R: 8.314 J/mol•K r1: 0ºC/min r2: 0ºC/min Tf: 30.4ºC Ti: 28.4ºC Determine the calorimeter constant (in J/ºC). Report your answer in 2 decimal places.What is ΔHsys for a reaction at 51.4 °C with ΔSsurr = 749 J mol-1 K-1 ? Express your answer in kJ mol-1 to at least two significant figures.Calculate the molar volume of the liquid and the vapor (both saturated) using the Redlich-Kwong (modified by Soave) (SKR) equation for the following cases: Propane at 40° C with saturated pressure = 13.71 bar. n-Butane at 100°C wiwth saturated pressure = 15.41 bar. Isobutane at 90° C with saturated pressure = 16.54 bar. Chlorine at 60° C with saturated pressure = 18.21 bar.
- A fuel has the following volumetric analysis: CH4 = 68% C2H6 = 32% Assume complete combustion with 15% excess aur at 101.325 kPa and 27 degrees dry bulb temperature. What is the total moles in the products of combustion?For the dissolution of LiCl in water, ΔHsoln = -37 kJ/mol.Which term would you expect to be the largest negativenumber: ΔHsolvent, ΔHsolute, or ΔHmix?Chlorodifluoromethane (CHF2Cl) was widely used in the compression/cooling circuits of refrigeration or air-conditioning systems. Since the discovery that such compounds (HCFCs and CFC's) released into the atmosphere were a major cause of depletion of stratospheric ozone, newer refrigeration systems make use of certain hydrofluorocarbons (HFCs), which are degraded in the lower atmosphere, instead. Often, mixtures of such compounds are used. Suppose a sample of refrigerant gas consisting of a simple mixture of the gases pentafluoroethane (C2HF5) and difluorormethane (CH2F2) has a density of 3.06 g/L at 14 °C and 0.974 atm. Calculate the average molecular mass for this sample
- Chlorodifluoromethane (CHF2Cl) was widely used in the compression/cooling circuits of refrigeration or air-conditioning systems. Since the discovery that such compounds (HCFCs and CFC's) released into the atmosphere were a major cause of depletion of stratospheric ozone, newer refrigeration systems make use of certain hydrofluorocarbons (HFCs), which are degraded in the lower atmosphere, instead. Often, mixtures of such compounds are used. Suppose a sample of refrigerant gas consisting of a simple mixture of the gases pentafluoroethane (C2HF5) and difluorormethane (CH2F2) has a density of 1.43 g/L at 26 °C and 0.405 atm. Calculate the average molecular mass for this sample. Calculate the volume percentage of CH2F2 in the sample.Chlorodifluoromethane (CHF2Cl) was widely used in the compression/cooling circuits of refrigeration or air-conditioning systems. Since the discovery that such compounds (HCFCs and CFC's) released into the atmosphere were a major cause of depletion of stratospheric ozone, newer refrigeration systems make use of certain hydrofluorocarbons (HFCs), which are degraded in the lower atmosphere, instead. Often, mixtures of such compounds are used. Suppose a sample of refrigerant gas consisting of a simple mixture of the gases pentafluoroethane (C2HF5) and 111-trifluoroethane (C2H3F3) has a density of 2.39 g/L at 23 °C and 0.593 atm. 1. Calculate the average molecular mass for this sample. 2. Calculate the volume percentage of C2H3F3 in the sample.Chlorodifluoromethane (CHF2Cl) was widely used in the compression/cooling circuits of refrigeration or air-conditioning systems. Since the discovery that such compounds (HCFCs and CFC's) released into the atmosphere were a major cause of depletion of stratospheric ozone, newer refrigeration systems make use of certain hydrofluorocarbons (HFCs), which are degraded in the lower atmosphere, instead. Often, mixtures of such compounds are used. Suppose a sample of refrigerant gas consisting of a simple mixture of the gases pentafluoroethane (C2HF5) and 111- trifluoroethane ((C2H3F3) has a density of1.95 g/L at 23 °C and 0.432 atm. Calculate the average molecular mass for this sample. Calculate the volume percentage of C2H3F3 in the sample.
- Chlorodifluoromethane (CHF2Cl) was widely used in the compression/cooling circuits of refrigeration or air-conditioning systems. Since the discovery that such compounds (HCFCs and CFC's) released into the atmosphere were a major cause of depletion of stratospheric ozone, newer refrigeration systems make use of certain hydrofluorocarbons (HFCs), which are degraded in the lower atmosphere, instead. Often, mixtures of such compounds are used. Suppose a sample of refrigerant gas consisting of a simple mixture of the gases pentafluoroethane (C2HF5) and difluorormethane (CH2F2) has a density of 2.99 g/L at 22 °C and 0.810 atm. Calculate the average molecular mass for this sample.8.94×101 amu Calculate the volume percentage of CH2F2 in the sample.Chlorodifluoromethane (CHF2Cl) was widely used in the compression/cooling circuits of refrigeration or air-conditioning systems. Since the discovery that such compounds (HCFCs and CFC's) released into the atmosphere were a major cause of depletion of stratospheric ozone, newer refrigeration systems make use of certain hydrofluorocarbons (HFCs), which are degraded in the lower atmosphere, instead. Often, mixtures of such compounds are used. Suppose a sample of refrigerant gas consisting of a simple mixture of the gases pentafluoroethane (C2HF5) and difluorormethane (CH2F2) has a density of 3.06 g/L at 14 °C and 0.974 atm. Calculate the volume percentage of CH2F2 in the sample.By the use of Henderson Hasselbalch equation; pH = pKa + log{[acetate ion]/[acetic acid]} 4.5 = 4.75 + log{[0.10 M]/[acetic acid]} -0.25 = log{[0.10 M]/[acetic acid]} [Acetic acid] = 0.10 M/ 10-0.25 [Acetic acid] = 0.10 M/0.56 [Acetic acid] = 0.1786 M Moles of sodium acetate dissolved in 250 mL buffer solution = 0.10 M× (250mL/1000mL) × 1L = 0.025 mol Weight (w) of sodium acetate (purity 100%) dissolved to prepare 250 mL of solution with buffer concentration of 0.10 M is calculate as follow; w100% = 0.025 mol × 82.0343 g/mol = 2.051 g Weight (w) of sodium acetate (purity 99%) is calculate as follow; w99% = 2.051 g× (100/99) = 2.072 g What was the volume of 6.12 M acetic acid HC2H3O2 needed to prepare the 250 mL acetic acid/acetate ion buffer solution required in this part? Show your calculations.