How many delectrons (nof dn) are in the central metal ion in (a) [Ru(NH3)5Cl]SO4; (b) Na2[Os(CN)6];(c) [Co(NH3)4CO3I]?

Q: Rhol(PPhs)s 9volume eICCtronsinRn in Cr which are The L-type ligands? Oxidanon State of Rn,cr…

A: The L type ligands in [RhCl(PPh3)3] is PPh3; i.e. triphenylphosphine. The L type ligand in Cr(CO)6…

Q: Is there a way to tell which ligands are strong-field and which are weak-field,

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Q: Draw the structures and give the stock names of complexes that can satisfy the conditon: 1.…

A: Ionization isomers in coordination complexes are identified by the ligands present outside the…

Q: Heating 3.0 mol of a coordination compound gives 1.5 mol of ammonia, 3.0 mol of water 1.5 mol of HCl…

A: The compounds in which the metal atom is surrounded by the ligands is known as coordination…

Q: hen cobalt(II) chloride is treated, under certain condition, with the bidentate ligand,…

A: Oxidation number is the total number of electrons gain or loses by an element when they form…

Q: If you want to use any of the [IrCl(CO)(PPh3)2] and [(η6-C6H6)Cr(CO)3] complexes as a catalyst in…

A: The given compound are organometallic compound. We know if the total electron count of the metal is…

Q: (d) [Cr(OH)2]¿** ions are pale blue-green but chromate (Cr,0,) ion is an intense yellow in colour.…

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Q: When cobalt(II) chloride is treated, under certain condition, with the bidentate ligand,…

A: A metal possesses two types of valencies -  primary and secondary. The combining power of a metal…

Q: When Cr(CO)5(PH3) and Cr(CO)5(NH3) are oxidized by one electron: a. What is the change in LFSE? b.…

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Q: Write the state of hybridisation, the shape and the magnetic behaviour of the following complex…

A: (i) [Cr(NH3)4Cl2]Cl: Hybradisation of [Cr(NH3)4Cl2]Cl is d2sp3 Geometry of [Cr(NH3)4Cl2]Cl is…

Q: In the chemical reaction of Na2CO3 + Pb(NO3)2, the resulting product is ___________?

A: It is an example of double decomposition reaction as precipitation reaction  All salts of nitrate…

Q: 6a. Some ligands are multifunctional; that is, they have two or more atoms which can bind to the…

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Q: 2. Ferrocyanide and ferricyanide are a particular kind of transition metal complex. State what that…

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Q: Consider the compound (C8H8)Ru(CO)3 which is likely to be the best description of the C8H8 ligand ?

A: The stability of any organometallic compound is given by Effective Atomic Number (EAN Rule).…

Q: Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionization isomers. (ii). Calculate…

A: Isomers are those compounds which have same chemical formula but they are different from each other.…

Q: What is the coordination number of cobalt in [Co(en)2Br21Br? (ethylenediamine, en H2NCH2CH2NH2)

A: Topic-- Coordination no in the Co-ordination  Complex

Q: 3+ (d) [Cr(OH)2]6* ions are pale blue-green but chromate (Cr,O,) ion is an intense yellow in colour.…

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Q: The CrF6^4- ion is known to have four unpaired electrons. State and explain whether the fluoride…

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Q: 2. Red crystalline [NiCl,(PPh,CH,Ph)2] is diamagnetic. On heating to 387 K for 2 hours, a blue-…

A: In this complex, nickel is in +2 oxidation state and it has valence shell electronic configuration…

Q: Which of the following ligands could form chelates? Indicate also the donor atom for each ligand. 1.…

A: As per our guidelines we can solve only first question. Please re-post other questions. Chelating…

Q: 2. Give two authentic examples of tetragonal elongated paramagnetic octahedral Cr(IV) complexes by…

A: The two authentic examples of tetragonal elongated paramagnetic octahedral Cr(IV) complexes has to…

Q: Construct a mode | of [Cr (C2 O4 Make sure are linked to donor atoms to indicate how the atorms…

A: The IUPAC name of this compound is Tris Oxalato chromium. It is a coordination compound. there is a…

Q: By taking into account the following complexes: A) [Co(en):]³* B)[CoCl3Br3]+ a) Give the oxidation…

A: In this question, we have to find out the correct answer of given problem by the help of the…

Q: When water ligands in [Ti(H2O)6]3+ are replaced by CN- ligands to give [Ti(CN)6]3-, the maximum…

A: [Ti(H2O)6]3+ is an octahedral complex and ligand H2O is a weak field ligand. [Ti(CN)6]3- is also an…

Q: (d) Based on crystal field stabilisation energy considerations, are FeCr204 and CuCr204, likely to…

A: The correct answer is given below

Q: Explain why, for the same metallic cation and the same ligands, the energy of the binding field is…

A: The question is based on the concept of coordination chemistry. We have to explain the low binding…

Q: Pyridine (CsHgN), abbreviated py, is the molecule N: (a) Would you expect pyridine to act as a…

A: Ligands Ligands in the coordinated complex is the ion or neutral molecule that act as the lewis base…

Q: Heating 2.0 mol of a coordination compound gives 1.0mol NH3, 2.0 mol H2O, 1.0 mol HCl, and 1.0…

A: The chemical equation must be:

Q: Pyridine (C5H5N), abbreviated py, Would you expect pyridine to act as a monodentate or bidentate…

A: Ligands are electron rich species. The electrons are donated to the central metal atom. The given…

Q: When cobalt (II) chloride is treated, under certain conditions, with the bidentate ligand,…

A: i) Let the oxidation state of Co be x, the bidentate ligand, NH2CH2CH2NH2, is a neutral species so…

Q: Explain how experimental determination of the number of geometric isomers of [Co(NH3)4Cl]2+ would…

A: Coordination chemistry is the study of compounds having a central atom attached to certain number of…

Q: [CoF6]3- absorbs 700 nm (red) radiation whereas [Co(H2O)6]3+ absorbs 600 nm (orange) radiation.…

A: The crystal field energy diagram f the given complexes is drawn as follows:

Q: Suppose that you want to determine whether a ligand X is a weak-field or strong-field ligand. Would…

A: Strong field ligand are able to pair the electrons while weak field ligand are not able to pair…

Q: What are the characters for the operations C2, C4, σd, and σv(xz) respectively, on the LCAO Ψ(L1+L3)…

A: Cn is a rotation of (360/n)". C2= 180°rotation, C4= 90°rotation

Q: In what directions do you expect the bond length andvibrational frequency of a free CO molecule to…

A: Interpretation - In what directions the bond length and vibrational frequency of a free CO molecule…

Q: Which of the following oxides is expected to exhibit a strong Jahn-Tell distortion? In all cases,…

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Q: y8gngu. Amino acids can act as ligands toward transition metal ions. The simplest amino acid is…

A: Ligands are the electron donating neutral or anionic group that donates the atleast one electron…

Q: A coordination compound has the following composition (by mass %): 23.53% Co; 42.47% Cl, and 34.00%…

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Q: Oxyhemoglobin, with an O2 bound to iron, is a low-spin Fe(II) complex; deoxyhemoglobin, without the…

A: Oxyhemoglobin and deoxyhemoglobin are derivatives of hemoglobin. Both are octahedral complexes. One…

Q: In [Cr(NH₃)₆]Cl₃, the [Cr(NH₃)₆]³⁺ ion absorbs visiblelight in the blue-violet range, and the…

A: In [Cr(NH₃)₆]Cl₃, the [Cr(NH₃)₆]³⁺ ion absorbs visible light in the blue-violet range, and the…

Q: The compound Cr(en)2(OH)2Cl has been prepared in several isomeric forms: Isomer A is optically…

A: Given compound Cr(en)2(OH)2Cl isomer A  optically inactive and undergoes no reaction with either…

Q: (a) Draw labelled d-orbital splitting diagrams for the metal centres in [CO(OH₂)6]Cl2 and…

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Q: Which d orbital on M (center metal) is capable of having a bonding interaction with the ligand group…

A: dx2-y2  is capable of forming bonding interaction with the ligands because ligands approach or…

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.