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- The iron content of hemoglobin is determined by destroying the hemoglobin molecule and producing small water-soluble ions and molecules. The iron in the aqueous solution is reduced to iron(II) ion and then titrated against potassium permanganate. In the titration, iron(ll) is oxidized to iron(III) and permanganate is reduced to manganese(II) ion. A 5.00-g sample of hemoglobin requires 32.3 mL of a 0.002100 M solution of potassium permanganate. The reaction with permanganate ion is MnO4(aq)+8H+(aq)+5Fe2+(aq)Mn2+(aq)+5Fe3+(aq)+4H2O What is the mass percent of iron in hemoglobin?The carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.Tartaric acid, H2C4H4O6, is a diprotic acid that naturally occurs in the production of apple wine. Emma was tasked to find out the acid content in a 50.0 mL wine sample by titrating it with a standardized solution of NaOH. She was able to establish the working concentration of the NaOH solution by using 17.61 mL of NaOH to titrate a primary standard of KHP that weighed 1.501 g. The grams and %w/w of Tartaric acid present in the 50.0 mL wine sample were then determined by titrating a 12.50 mL aliquot using 21.78 mL of the standardized NaOH solution. H2C4H4O6 (aq) + 2NaOH (aq) ↔ Na2C4H4O6 (aq) + 2H2O (l) Assume that the density of the wine sample is 1.000 g/mL MM of KHP = 204.22 g/mol MM of H2C4H4O6 = 150.087 g/mol What is the molar concentration of the prepared NaOH solution?…
- Whilst working in the pharmacy aseptic unit you are asked to prepare 5 litres of a solution containing potassium ions 1 mmol/mL. What weight of potassium chloride is required?The fish canning industry has a waste effluent with the specification as follows: BOD5 = 150 mg/L, COD = 230 mg/L, CaCO3 = 65 mg/L, pH = 7,0, Odor = 11 (TON, where every 1 mg/L ammonia-N equals to 2 TON), Oil = 300 mg/L. Give recommendation of what kind of treatment (physical and chemical steps) is required to treat the wastewater, and why do you select those steps.Tartaric acid, H2C4H4O6, is a diprotic acid that naturally occurs in the production of wine. Jose was tasked to find out the acid content in a 100.0 mL wine sample by titrating it with a standardized solution of NaOH. He was able to establish the working concentration of the NaOH solution by using 35.21 mL of it to titrate a primary standard of KHP that weighed 3.001 g. The grams and %w/w of Tartaric acid present in the 100.0 mL wine sample were then determined by titrating a 25.00 mL aliquot using 43.56 mL of the standardized NaOH solution. H2C4H4O6 (aq) + 2NaOH (aq) ↔ Na2C4H4O6 (aq) + 2H2O (l) Assume that the density of the wine sample is 1.000 g/mL MM of KHP = 204.22 g/mol MM of H2C4H4O6 = 150.087 g/mol What is the molar concentration of the prepared NaOH solution?…
- Come up with a dilution scheme for a test solution starting from 1000 μg/mL Mn stock solution so that the concentration of permanganate in the solution just prior to measurement is approx. 20 μg/mL MnO4-. Carefully read the units!In the standardization of HCl using pure anhydrous sodium carbonate as the primarystandard for methyl orange as an indicator, 1.0 mL HCl was found to be equivalent to 0.05gof sodium carbonate (MW =106). The normality of HCl is:The Kc for the reaction 2A (aq) ⇌ 3 B (aq) is 0.085. What is Kc for the reaction 3 B (aq) ⇌ 2A (aq)?
- Malic acid (C4H6O5) is a dicarboxylic acid that naturally occurs in the production of bignay wine. Maria was tasked to find out the acid content in a 200.0 mL wine sample by titrating it with a standardized solution of KOH. He was able to establish the working concentration of the KOH solution by using 39.12 mL of it to titrate a primary standard of KHP that weighed 3.021 g. The grams and %w/w of Malic acid present in the 200.0 mL wine sample were then determined by titrating a 20.00 mL aliquot using 48.95 mL of the standardized KOH solution. C4H6O5 (aq) + 2KOH (aq) ↔ K2C4H4O5 (aq) + 2H2O (l) Assume the density of the wine sample is 1.000 g/mL MM of KHP = 204.22 g/mol MM of C4H6O5 = 134.0874 g/mol ? What is the molar concentration of the prepared KOH solution?…Malic acid (C4H6O5) is a dicarboxylic acid that naturally occurs in the production of bignay wine. Maria was tasked to find out the acid content in a 200.0 mL wine sample by titrating it with a standardized solution of KOH. He was able to establish the working concentration of the KOH solution by using 39.12 mL of it to titrate a primary standard of KHP that weighed 3.021 g. The grams and %w/w of Malic acid present in the 200.0 mL wine sample were then determined by titrating a 20.00 mL aliquot using 48.95 mL of the standardized KOH solution. C4H6O5 (aq) + 2KOH (aq) ↔ K2C4H4O5 (aq) + 2H2O (l) Assume the density of the wine sample is 1.000 g/mL MM of KHP = 204.22 g/mol MM of C4H6O5 = 134.0874 g/mol What is the molar concentration of the prepared KOH solution?…A 12.5 mL portion of a base solution of an element from Group 2A is diluted to 500 mL, and the resulting concentration of this solution is determined to be 0.125 M. What is the normality of the original solution?