I know the product and the arrow pushing for both reactions, but I need assistance with the FMO energy diagrams. I know the first one is a normal Diels alder reaction and the second one is Inverse electron demand Diels–Alder reaction. But, I am confused about how to draw them out.

Q: Label attached diene as reactive or unreactive in a Diels–Alder reaction

A: Diels-Alder reaction is an important reaction of chemistry. It helps in synthesis of several organic…

Q: (a) (b) Нeat Ethene

A: (a) The [4+2] cycloaddition reaction taking place between diene and dienophile from HOMO of a diene…

Q: Complete the following Diels-Alder reactions. No mechanism. Explain why in some cases no reaction…

A: The Diels alder is a cycloaddition reaction of diene (involves 4 pi electrons) and a dienophile…

Q: The Diels-Alder reaction is not the only pericyclic reaction involving the cyclic flow of six…

A:

Q: HEAT

A: In this question, we want to draw mechanism for this reaction.  You can see details mechanism below.…

Q: We mentioned in the chapter opener (p. 1198) that tetrodotoxin has been synthesized using a…

A: The given reaction is,

Q: Diels-Alder

A:

Q: With this in mind, draw the product of each intramolecular Diels-Alder reaction. ÇOOCH, a. b.

A: The reaction between conjugated diene with substituted alkene (dienophile) results in the formation…

Q: Compounds containing triple bonds are also Diels–Alder dienophiles.With this in mind, draw the…

A: Diels-Alder reaction is type of cycloaddition pericyclic reaction . It is [4+2] type cycloaddition…

Q: One of the following Diels-Alder reactions will occur more rapidly than the other. Draw the major,…

A: The answer is as follows:

Q: Rank the following dienes in their rate of reaction with the same dienophile in a Diels-Alder…

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Q: Draw the diene and dienophile that are needed to prepare the following Diels-Alder product.

A: The Diels–Alder reaction is the reaction between a conjugated diene and an dienophile to form a…

Q: Which of the following compounds can arise directly from a Diels-Alder reaction? Please circle any…

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Q: What is the major product of the Diels Alder reaction shown in the box? ? +

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Q: 1. Write in the product of this Diels-Alder reaction. Be sure to include stereochemistry where…

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Q: see the attached question and out of these 3 comounds, which one is the best dienophile ?

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Q: Classify the following diene, as an aid to understanding its reactivity. Conjugated Diene Cumulated…

A: The three different types of dienes are  1) Conjugated dienes  2) cumulated dienes 3) Isolated…

Q: Which of these dienes is the least stable?

A: The stabolity of diene is conjugated>non-conjugated diene is more stable than non-conjugated.

Q: Deconstruct the given Diels–Alder adduct. Draw the reactants (A and B), in any order, that would be…

A: In diels alder reaction , there are two reactant which combines to give an adduct.  The two…

Q: 1. In the Diels-Alder reaction below, six isomeric products A-F are depicted. However, only one of…

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Q: In Part 1, select the two new o bonds that were formed in this Diels-Alder reaction. In Parts 2 and…

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Q: Rank the following dienes in order of increasing heat of hydrogenation.

A: The given compounds are,

Q: The bicyclic compound shown undergoes a Diels-Alder reaction with a dienophile to produce the…

A: Diels alder  reaction is pericylic reaction which goes via concerted pathway where bond breaking and…

Q: For each pericyclic reaction below, write in the box whether the reaction is Diels-Alder,…

A: Given reactions: We have to find out whether they are Diels-Alder, Electrocyclic or Sigmatropic and…

Q: For the Diels-Alder reactions show the major organic product. Be sure to show all stereochemistry…

A:

Q: 2 Draw the retro Diels-Alder mechanism and product for each of the compounds shown here. Which retro…

A: Retro Diels-Alder reaction is reverse of the diels alder reaction. A diels alder reaction is a (4+2)…

Q: CH3 CH3

A: Answer:- This question is answered by using the simple concept stereochemistry of Diels Alder…

Q: Classify the following diene, as an aid to understanding its reactivity. O Conjugated Diene…

A: Conjugated diene: In this diene alternate single and double bonds are present. Cumulative diene: In…

Q: Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product…

A: The reaction given is,

Q: Provide the starting diene and dienophile for the Diels-Alder pro

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Q: OMe Classify the following diene, as an aid to understanding its reactivity. Conjugated Diene…

A: The 3 types of dienes are  1) Conjugated dienes  2) Cumulated dienes  3) Isolated dienes

Q: Consider a traditional Diels Alder reaction noting it's methodology and synthetic tactical. Then…

A: A question based on green chemistry that is to be accomplished.

Q: The rate of a Diels-Alder reaction is favored by select all that apply electron withdrawing…

A: In Diels Alder reaction mechanism, electrons from dienophile attack on Carbon first of diene , thus…

Q: Q2. Draw the structures for the diene and dienophile you would use to synthesize each of the…

A: As per the name diene is a molecule with alternate double bonds. And the dienophile is the molecule…

Q: final

A: Please find the file attached for explanation

Q: What combination of diene and dienophile undergoes Diels-Alder reaction to give   adduct?

A: The combination of diene and dienophile undergoes Diels-Alder reaction to give the following adduct.

Q: Which of the structures below is the major product obtained from the following Diels-Alder reaction.…

A: To determine the major product with stereochemistry of the given reaction.

Q: Deconstruct the given Diels–Alder adduct. Draw the reactants, in any order, that would be needed to…

A:

Q: a. When HBr adds to a conjugated diene, what is the rate-determining step? b. When HBr adds to a…

A: The addition of the H+ is basically the rate determining step of the reaction. Hence the product…

Q: Perform retrosynthesis on the following molecule to break it into its original starting materials.…

A: Final compound can be obtained from its Boc-protected (A). A can be obtained form the the reduction…

Q: How do I rank these from best to poorest leaving group? Do I base it in the size of the…

A: We have to rank leaving group tendency :-

Q: Intramolecular Diels-Alder reactions are possible when a substrate contains both a 1,3-diene and a…

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Q: b) Support your answer with the appropriate energy diagrams. (Energy diagram should show two…

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Q: APPLY STEREOCHEMISTRY WHEN APPLICABLE: Does each reaction occur from SN1 or 2? What are the organic…

A: the solution is as follows:

Q: The reaction shown below yields a mixture of two Diels-Alder adducts. In the box below draw the…

A: The reaction given is,

Q: no reaction

A: Diels-Alder reaction: The Diels–Alder reaction is a reaction between a conjugated diene and a…

Q: Draw the (pericyclic) reaction (reaction 1), including all mechanistic steps, that lead from the…

A: To draw the mechanistic steps of reaction 1, show all isomers that can be formed and determine the…