i. The ionization energy of fluorine (F) is ~1700 kJ/mol, while the ionization energy of difluorine (F2) is ~1500 kJ/mol. ii. Bez cannot exist, while both Be2* and Be,¯ can exist. The longest wavelength of light that can be absorbed by N2 is ~80 nm, while the longest wavelength of light that can be absorbed by F2 is ~100 nm. (No calculations are required for this). ii.

Chemistry: An Atoms First Approach
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Author:Steven S. Zumdahl, Susan A. Zumdahl
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Chapter4: Molecular Structure And Orbitals
Section: Chapter Questions
Problem 119CP
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Use MO theory to explain the following:
O2P
*
2p, 2pх 2ру
TT 2p
2р, 2рx 2ру
2р, 2рх 2ру
2р, 2рх 2ру
O 2P
O 2P
TT 2p
O2s
02s
2s
2s
2s
2s
O2s
O2s
i. The ionization energy of fluorine (F) is ~1700 kJ/mol, while the ionization
energy of difluorine (F2) is ~1500 kJ/mol.
+
iii. The longest wavelength of light that can be absorbed by N2 is ~80 nm, while
the longest wavelength of light that can be absorbed by F2 is ~100 nm. (No
calculations are required for this).
ii. Bez cannot exist, while both Be,* and Be,¯ can exist.
Transcribed Image Text:Use MO theory to explain the following: O2P * 2p, 2pх 2ру TT 2p 2р, 2рx 2ру 2р, 2рх 2ру 2р, 2рх 2ру O 2P O 2P TT 2p O2s 02s 2s 2s 2s 2s O2s O2s i. The ionization energy of fluorine (F) is ~1700 kJ/mol, while the ionization energy of difluorine (F2) is ~1500 kJ/mol. + iii. The longest wavelength of light that can be absorbed by N2 is ~80 nm, while the longest wavelength of light that can be absorbed by F2 is ~100 nm. (No calculations are required for this). ii. Bez cannot exist, while both Be,* and Be,¯ can exist.
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