If Ksp (AgBr) = 4.0 x 10-¹3, and if, for the Ag+ + NH3 complex system (Ag+ + NH3 ⇒ [AgNH3]*; [AgNH3]+ + NH3 = [Ag(NH3)2]*), for 0.10 M NH3, P = 4.0 x 10-6, B₁ = 1.0 x 10-³, and ₂ = 1.0 x 10°, then what is the solubility of AgBr in 0.10 M NH3? Comment on any assumptions you made in your calculations. 1

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter17: Complexation And Precipitation Reactions And Titrations
Section: Chapter Questions
Problem 17.39QAP
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If Ksp (AgBr) = 4.0 x 10-13, and if, for the Ag+ + NH3 complex system (Ag+ + NH3
⇒ [AgNH3]; [AgNH3]+ + NH3 = [Ag(NH3)2]*), for 0.10 M NH3, B = 4.0 x 10-6,
B₁ = 1.0 x 10-³, and ₂ = 1.0 x 100, then what is the solubility of AgBr in 0.10 M
NH3? Comment on any assumptions you made in your calculations.
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Transcribed Image Text:If Ksp (AgBr) = 4.0 x 10-13, and if, for the Ag+ + NH3 complex system (Ag+ + NH3 ⇒ [AgNH3]; [AgNH3]+ + NH3 = [Ag(NH3)2]*), for 0.10 M NH3, B = 4.0 x 10-6, B₁ = 1.0 x 10-³, and ₂ = 1.0 x 100, then what is the solubility of AgBr in 0.10 M NH3? Comment on any assumptions you made in your calculations. -
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