If the wavenumber of the J = 3 ← 2 rotational transition of 1H35Cl, which may be considered as a rigid rotator, is 63.56 cm−1 calculate the moment of inertia and the bond length of the molecule. [Note: m(1H) = 1.0078 u and m(35Cl) = 34.9688 u.]

If the wavenumber of the J = 3 ← 2 rotational transition of 1H35Cl, which may be considered as a rigid rotator, is 63.56 cm−1 calculate the moment of inertia and the bond length of the molecule. [Note: m(1H) = 1.0078 u and m(35Cl) = 34.9688 u.]

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter20: Molecular Spectroscopy And Photochemistry

Section: Chapter Questions

Problem 14P

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Question

If the wavenumber of the J = 3 ← 2 rotational transition of ¹H³⁵Cl, which may be considered as a rigid rotator, is 63.56 cm⁻¹ calculate the moment of inertia and the bond length of the molecule.
[Note: m(1H) = 1.0078 u and m(35Cl) = 34.9688 u.]

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