In a study of the conversion of methyl isonitrile to acetonitrile in the gas phase at 250 °C CH3NC(g) CH3CN(g) the concentration of CH3NC was followed as a function of time. It was found that a graph of In[CH3NC] versus time in seconds gave a straight line with a slope of -4.20×10s and a y-intercept of -2.27 . Based on this plot, the reaction is vJorder in CH3NC and the rate constant for the reaction is

Chemical Principles in the Laboratory
11th Edition
ISBN:9781305264434
Author:Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Publisher:Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Chapter21: Rates Of Chemical Reactions, Ii. A Clock Reaction
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In a study of the conversion of methyl isonitrile to acetonitrile in the gas phase at 250 °C
CH3NC(g) CH3CN(g)
the concentration of CH3NC was followed as a function of time.
It was found that a graph of In[CH3NC] versus time in seconds gave a straight line with a slope of -4.20×10s and a y-intercept of -2.27 .
Based on this plot, the reaction is
vJorder in CH3NC and the rate constant for the reaction is
Transcribed Image Text:In a study of the conversion of methyl isonitrile to acetonitrile in the gas phase at 250 °C CH3NC(g) CH3CN(g) the concentration of CH3NC was followed as a function of time. It was found that a graph of In[CH3NC] versus time in seconds gave a straight line with a slope of -4.20×10s and a y-intercept of -2.27 . Based on this plot, the reaction is vJorder in CH3NC and the rate constant for the reaction is
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