In a study of the gas phase decomposition of nitrosyl chloride at 400 K NOCI(g)NO(g) + ½ Cl2(g) the following data were obtained: NOCI], M seconds 5.08x10-2 2.54x10-2 3.75x104 1.27x10-2 1.13×105 6.35x10-3 2.63x105 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 5.08×102 M is Mis Js and when the starting concentration is 2.54×10-2 (2) The average A(1/[NOCI]) / At from t= 0 s to t = 3.75×104 s is The average A(1/[NOCI]) / At from t= 3.75×104 s to t = 1.13×105 s S 1s (3) Based on these data, the rate constant for this | order reaction is

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Chapter12: Kinetics
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In a study of the gas phase decomposition of nitrosyl chloride at 400 K
NOCI(g)NO(g) + ½ Cl2(g)
the following data were obtained:
NOCI], M
seconds
5.08x10-2
2.54x10-2
3.75x104
1.27x10-2
1.13×105
6.35x10-3
2.63x105
Hint: It is not necessary to graph these data.
(1)
The observed half life for this reaction when the starting concentration is 5.08×102 M is
Mis
Js and when the starting concentration is 2.54×10-2
(2)
The average A(1/[NOCI]) / At from t= 0 s to t = 3.75×104 s is
The average A(1/[NOCI]) / At from t= 3.75×104 s to t = 1.13×105 s
S 1s
(3)
Based on these data, the rate constant for this
| order reaction is
Transcribed Image Text:In a study of the gas phase decomposition of nitrosyl chloride at 400 K NOCI(g)NO(g) + ½ Cl2(g) the following data were obtained: NOCI], M seconds 5.08x10-2 2.54x10-2 3.75x104 1.27x10-2 1.13×105 6.35x10-3 2.63x105 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 5.08×102 M is Mis Js and when the starting concentration is 2.54×10-2 (2) The average A(1/[NOCI]) / At from t= 0 s to t = 3.75×104 s is The average A(1/[NOCI]) / At from t= 3.75×104 s to t = 1.13×105 s S 1s (3) Based on these data, the rate constant for this | order reaction is
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