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The total pressure of the following system is used to monitor the progress of the chemical reaction. SO₂Cl₂(g) → SO₂(g) + Cl₂(g) The reaction is initiated, and the following data are obtained: Time (h) 0 3 6 9 12 15 11.07 14.79 17.26 PTotal (kPa) 18.90 19.99 20.71 Pso₂Cl₂ Pso₂ Pctz Additional information: As the reaction proceeds, stoichiometry dictates that for every mole of SO₂Cl₂ that dissociates one mole of each of SO₂ and Cl₂ is produced. Defining the extent of dissociation/reaction as , and the initial pressure as Po, the total pressure is given by: Ptotal = Pso₂Cl₂ + Pso₂+ Pct₂ = (Po-5)+ 5 + 5 a) Calculate the pressure of each component at each time interval, i.e. complete the above table. b) Use a graphical method and determine what the order of the reaction is with respect to SO₂Cl₂? (i) Show the plot as well as the linear fit of the data. (ii) Motivate your answer. c) Determine the rate constant for this reaction. d) Give the rate equation describing the reaction. e) What is the half-life of this reaction? Show your calculation. f) How long will the reaction take to come to an end? Show your calculation/derivation of the rate equation in (d).

The total pressure of the following system is used to monitor the progress of the chemical reaction. SO₂Cl₂(g) → SO₂(g) + Cl₂(g) The reaction is initiated, and the following data are obtained: Time (h) 0 3 6 9 12 15 11.07 14.79 17.26 PTotal (kPa) 18.90 19.99 20.71 Pso₂Cl₂ Pso₂ Pctz Additional information: As the reaction proceeds, stoichiometry dictates that for every mole of SO₂Cl₂ that dissociates one mole of each of SO₂ and Cl₂ is produced. Defining the extent of dissociation/reaction as , and the initial pressure as Po, the total pressure is given by: Ptotal = Pso₂Cl₂ + Pso₂+ Pct₂ = (Po-5)+ 5 + 5 a) Calculate the pressure of each component at each time interval, i.e. complete the above table. b) Use a graphical method and determine what the order of the reaction is with respect to SO₂Cl₂? (i) Show the plot as well as the linear fit of the data. (ii) Motivate your answer. c) Determine the rate constant for this reaction. d) Give the rate equation describing the reaction. e) What is the half-life of this reaction? Show your calculation. f) How long will the reaction take to come to an end? Show your calculation/derivation of the rate equation in (d).

Chemistry for Engineering Students
Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.58PAE
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09:00 Edit סם ⠀ 2 Assignment 3 (NCHE312) The total pressure of the following system is used to monitor the progress of the chemical reaction. SO₂Cl2(g) → SO₂(g) + Cl₂(g) The reaction is initiated, and the following data are obtained: 0 3 6 9 12 15 Time (h) PTotal (kPa) 14.79 17.26 18.90 11.07 19.99 20.71 Pso₂Cl₂ Pso₂ Pclz Additional information: As the reaction proceeds, stoichiometry dictates that for every mole of SO₂Cl₂ that dissociates one mole of each of SO₂ and Cl₂ is produced. Defining the extent of dissociation/reaction as E, and the initial pressure as Po, the total pressure is given by: Ptotal = Pso₂Cl₂ + Ps0₂ + Pcl₂ = (Po-5 + 5 + 5 a) Calculate the pressure of each component at each time interval, i.e. complete the above table. b) Use a graphical method and determine what the order of the reaction is with respect to SO₂Cl₂? (i) Show the plot as well as the linear fit of the data. (ii) Motivate your answer. c) Determine the rate constant for this reaction. d) Give the rate equation describing the reaction. e) What is the half-life of this reaction? Show your calculation. f) How long will the reaction take to come to an end? Show your calculation/derivation of the rate equation in (d). Convert your work into a single PDF file and upload it into your eFundi Dropbox folder. Deadline for submission: 08/06/2022 at 12pm DO W Mobile View Share PDF to DOC Tools Vol) LTE 4G x HJ Edit on PC
Transcribed Image Text:09:00 Edit סם ⠀ 2 Assignment 3 (NCHE312) The total pressure of the following system is used to monitor the progress of the chemical reaction. SO₂Cl2(g) → SO₂(g) + Cl₂(g) The reaction is initiated, and the following data are obtained: 0 3 6 9 12 15 Time (h) PTotal (kPa) 14.79 17.26 18.90 11.07 19.99 20.71 Pso₂Cl₂ Pso₂ Pclz Additional information: As the reaction proceeds, stoichiometry dictates that for every mole of SO₂Cl₂ that dissociates one mole of each of SO₂ and Cl₂ is produced. Defining the extent of dissociation/reaction as E, and the initial pressure as Po, the total pressure is given by: Ptotal = Pso₂Cl₂ + Ps0₂ + Pcl₂ = (Po-5 + 5 + 5 a) Calculate the pressure of each component at each time interval, i.e. complete the above table. b) Use a graphical method and determine what the order of the reaction is with respect to SO₂Cl₂? (i) Show the plot as well as the linear fit of the data. (ii) Motivate your answer. c) Determine the rate constant for this reaction. d) Give the rate equation describing the reaction. e) What is the half-life of this reaction? Show your calculation. f) How long will the reaction take to come to an end? Show your calculation/derivation of the rate equation in (d). Convert your work into a single PDF file and upload it into your eFundi Dropbox folder. Deadline for submission: 08/06/2022 at 12pm DO W Mobile View Share PDF to DOC Tools Vol) LTE 4G x HJ Edit on PC
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#(d)Give the rate equation describing the reaction. 
#(e)What is the half life of this reaction?Show your calculations. 
#(f) How long will the reaction take to come to an end? Show your calculations/derivation of the rate equation in (d). 

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1 of 1 Assignment 3 (NCHE312) The total pressure of the following system is used to monitor the progress of the chemical reaction. SO₂Cl₂(g) → SO2(g) + Cl₂(g) The reaction is initiated, and the following data are obtained: Time (h) PTotal (kPa) Pso₂cl₂ Ps0₂ Pclz 0 11.07 3 6 14.79 17.26 9 18.90 12 19.99 15 20.71 Additional information: As the reaction proceeds, stoichiometry dictates that for every mole of SO₂Cl₂ that dissociates one mole of each of SO₂ and Cl₂ is produced. Defining the extent of dissociation/reaction as E, and the initial pressure as Po, the total pressure is given by: Ptotal = Pso₂Cl₂ + Pso₂+ Pcl₂ = (Po-5)+5+5 Convert your work into a single PDF file and upload it into your eFundi Dropbox folder. Deadline for submission: 26/05/2023 at 12pm a) Calculate the pressure of each component at each time interval, i.e. complete the above table. b) Use a graphical method and determine what the order of the reaction is with respect to SO₂Cl₂? (i) Show the plot as well as the linear fit of the data. (ii) Motivate your answer. c) Determine the rate constant for this reaction. d) Give the rate equation describing the reaction. e) What is the half-life of this reaction? Show your calculation. f) How long will the reaction take to come to an end? Show your calculation/derivation of the rate equation in (d).
Transcribed Image Text:1 of 1 Assignment 3 (NCHE312) The total pressure of the following system is used to monitor the progress of the chemical reaction. SO₂Cl₂(g) → SO2(g) + Cl₂(g) The reaction is initiated, and the following data are obtained: Time (h) PTotal (kPa) Pso₂cl₂ Ps0₂ Pclz 0 11.07 3 6 14.79 17.26 9 18.90 12 19.99 15 20.71 Additional information: As the reaction proceeds, stoichiometry dictates that for every mole of SO₂Cl₂ that dissociates one mole of each of SO₂ and Cl₂ is produced. Defining the extent of dissociation/reaction as E, and the initial pressure as Po, the total pressure is given by: Ptotal = Pso₂Cl₂ + Pso₂+ Pcl₂ = (Po-5)+5+5 Convert your work into a single PDF file and upload it into your eFundi Dropbox folder. Deadline for submission: 26/05/2023 at 12pm a) Calculate the pressure of each component at each time interval, i.e. complete the above table. b) Use a graphical method and determine what the order of the reaction is with respect to SO₂Cl₂? (i) Show the plot as well as the linear fit of the data. (ii) Motivate your answer. c) Determine the rate constant for this reaction. d) Give the rate equation describing the reaction. e) What is the half-life of this reaction? Show your calculation. f) How long will the reaction take to come to an end? Show your calculation/derivation of the rate equation in (d).
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