In aqueous solution initially prepared by mixing 225 g H2O (density is 1.0 g/mL), 0.3 M C, and 0.1 M A takes a few minutes to reach the equilibrium at 67°C. 2 reactions occur in series and exist at equilibrium as follows; A (aq) + H2O (l) ⇌ B (aq) + C (aq) K1 = 8.3 x 10-8 B (aq) + H2O (l) ⇌ D (aq) + C (aq) K2 = 1.0 x 10-14 Determine mole fractions of A, B, C, and D at equilibrium

Introduction to General, Organic and Biochemistry
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ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
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Chapter7: Reaction Rates And Chemical Equilibrium
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Problem 7.81P
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In aqueous solution initially prepared by mixing 225 g H2O (density is 1.0 g/mL), 0.3 M C, and 0.1 M A takes a few minutes to reach the equilibrium at 67°C. 2 reactions occur in series and exist at equilibrium as follows;
A (aq) + H2O (l) ⇌ B (aq) + C (aq) K1 = 8.3 x 10-8
B (aq) + H2O (l) ⇌ D (aq) + C (aq) K2 = 1.0 x 10-14
Determine mole fractions of A, B, C, and D at equilibrium

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