In the presence of excess thiocyanate ion, SCN¯, the following reaction is first order in chromium(II) ion, Cr³+; the rate constant is 6.0 x 10-0 /s. Cr** (ag) + SCN¯ (aq) → Cr(SCN)²+ (ag) a. What is the half-life in hours? t1/2 hr b. How many hours would be required for the initial concentration of Cr³+ to decrease to 25.0% left? t25% left | hr c. How many hours would be required for the initial concentration of Cr*+ to decrease to 12.5% left? t12.5% left hr

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Chapter13: Rates Of Reaction
Section: Chapter Questions
Problem 13.65QP: In the presence of excess thiocyanate ion, SCN, the following reaction is first order in...
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In the presence of excess thiocyanate ion, SCN, the following
reaction is first order in chromium(III) ion, Cr**; the rate
constant is 6.0 x 10–0/s.
Cr*+ (ag) + SCN (ag) → Cr(SCN)2+ (ag)
a. What is the half-life in hours?
hr
b. How many hours would be required for the initial
concentration of Cr+ to decrease to 25.0% left?
t25% left =
hr
c. How many hours would be required for the initial
concentration of Cr+ to decrease to 12.5% left?
t12.5% left =|
hr
d. How many hours would be required for the initial
concentration of Cr³+ to decrease to 6.25% left?
to 25% left*
hr
e. How many hours would be required for the initial
concentration of Cr+ to do
case to 3.125
eft?
t3.125% left =
hr
Transcribed Image Text:In the presence of excess thiocyanate ion, SCN, the following reaction is first order in chromium(III) ion, Cr**; the rate constant is 6.0 x 10–0/s. Cr*+ (ag) + SCN (ag) → Cr(SCN)2+ (ag) a. What is the half-life in hours? hr b. How many hours would be required for the initial concentration of Cr+ to decrease to 25.0% left? t25% left = hr c. How many hours would be required for the initial concentration of Cr+ to decrease to 12.5% left? t12.5% left =| hr d. How many hours would be required for the initial concentration of Cr³+ to decrease to 6.25% left? to 25% left* hr e. How many hours would be required for the initial concentration of Cr+ to do case to 3.125 eft? t3.125% left = hr
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