Increasing the temperature of the reactants increases the fraction of the reacting species that collide with energies equal to or greater than the free energy/activation energy. Another factor that can affect whether or not molecules react is their orientation/bond length toward one another when they collide. Molecules with incorrect bond lengths/orientations will not react even if they successfully collide.

Introductory Chemistry For Today
8th Edition
ISBN:9781285644561
Author:Seager
Publisher:Seager
Chapter8: Reaction Rates And Equilibrium
Section: Chapter Questions
Problem 8.76E
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Increasing the temperature of the reactants increases the fraction of the reacting species that collide with energies equal to or greater than the free energy/activation energy. Another factor that can affect whether or not molecules react is their orientation/bond length toward one another when they collide. Molecules with incorrect bond lengths/orientations will not react even if they successfully collide.

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