Indicate whether each statement is true or false. (a) Thethird law of thermodynamics says that the entropy of aperfect, pure crystal at absolute zero increases with themass of the crystal. (b) “Translational motion” of moleculesrefers to their change in spatial location as a functionof time. (c) “Rotational” and “vibrational” motionscontribute to the entropy in atomic gases like He and Xe.(d) The larger the number of atoms in a molecule, themore degrees of freedom of rotational and vibrationalmotion it likely has.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter13: Spontaneous Processes And Thermodynamic Equilibrium
Section: Chapter Questions
Problem 22P: Use data from Appendix D to calculate the standardentropy change at 25°C for the reaction...
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Indicate whether each statement is true or false. (a) The
third law of thermodynamics says that the entropy of a
perfect, pure crystal at absolute zero increases with the
mass of the crystal. (b) “Translational motion” of molecules
refers to their change in spatial location as a function
of time. (c) “Rotational” and “vibrational” motions
contribute to the entropy in atomic gases like He and Xe.
(d) The larger the number of atoms in a molecule, the
more degrees of freedom of rotational and vibrational
motion it likely has.

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