isn't true that -OCH3 (methoxy group) The methoxy group is electron withdrawing by the inductive effect of the oxygen atom, since the electronegativity of oxygen is 2.6??? However in EAS, -OCH3 is EDG (electron donating group), why????????

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
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isn't true that -OCH3 (methoxy group) The methoxy group is electron withdrawing by the inductive effect of the oxygen atom, since the electronegativity of oxygen is 2.6??? However in EAS, -OCH3 is EDG (electron donating group), why????????

Activating
EDG
Reference
EWG
Deactivating
Most Activating
-NR₂
-NH₂
-OH
-ÖR
-NHCR
.ů
-ỌCR
-R
-C=CR₂
H
-H
-X
-
=
ů
-CH
-COR
요
-COH
요
-CC1
-CF3
-CEN
0=42=0 +2° +2°
OH
-NH₂
-
- NR3
Lo
Most Deactivating
Strongly Activating
Moderately Activating
Weakly Activating
Weakly Deactivating
Moderately Deactivating
Strongly Deactivating
ortho / para
directing
meta
directing
Transcribed Image Text:Activating EDG Reference EWG Deactivating Most Activating -NR₂ -NH₂ -OH -ÖR -NHCR .ů -ỌCR -R -C=CR₂ H -H -X - = ů -CH -COR 요 -COH 요 -CC1 -CF3 -CEN 0=42=0 +2° +2° OH -NH₂ - - NR3 Lo Most Deactivating Strongly Activating Moderately Activating Weakly Activating Weakly Deactivating Moderately Deactivating Strongly Deactivating ortho / para directing meta directing
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