It has been proposed that the gas NOC1 decomposes by the mechanism:kiNO2(g) + Cl(g)k-1NO2CI(g)NO2CI(g) + Cl(g) * NO2(g) + Cl2(g)k2Apply the Steady State Approximation to derive an expression for the concentration of theintermediate, Cl(g). Show your working out. States not required.

Steady state approximation: Steady state approximation is used to determine the rate law expression.…

It has been proposed that the gas NO;Cl decomposes by the mechanism: ki * NO2(g) + Cl(g) k1 NO:CI(g) NO:CI(g) + Cl(g) k2 NO:(g) + Cl2(g) Apply the Steady State Approximation to derive an expression for the concentration of the intermediate, Cl(g). Show your working out. States not required.

It has been proposed that the gas NO;Cl decomposes by the mechanism: ki * NO2(g) + Cl(g) k1 NO:CI(g) NO:CI(g) + Cl(g) k2 NO:(g) + Cl2(g) Apply the Steady State Approximation to derive an expression for the concentration of the intermediate, Cl(g). Show your working out. States not required.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter20: Kinetics

Section: Chapter Questions

Problem 20.91E: What are the rate laws of mechanisms 1 and 2 for oscillating reactions if the second reactions were...

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Question

It has been proposed that the gas NOC1 decomposes by the mechanism:
ki
NO2(g) + Cl(g)
k-1
NO2CI(g)
NO2CI(g) + Cl(g) * NO2(g) + Cl2(g)
k2
Apply the Steady State Approximation to derive an expression for the concentration of the
intermediate, Cl(g). Show your working out. States not required.

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