(iv) In transition metal complexes such as those in part (a)(i), what determines the wavelength of light absorbed. (v) Using the answers to (a)(i) to (a)(iv), explain why: • • The colour arising from d-d transitions in [Fe(OH₂)61³ is less intense than that arising from d-d transitions in [Fe(CN)]³. [Fe(OH₂)] absorbs light at a longer wavelength than [Fe(CN)]¹.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 11QRT
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(a) (i) State the oxidation state and d configuration for iron in the complex anion
[Fe(CN)
and the complex cation [Fe(OH₂)]³+.
Transcribed Image Text:(a) (i) State the oxidation state and d configuration for iron in the complex anion [Fe(CN) and the complex cation [Fe(OH₂)]³+.
(iv) In transition metal complexes such as those in part (a)(i), what determines the
wavelength of light absorbed.
(v) Using the answers to (a)(i) to (a)(iv), explain why:
• [Fe(OH₂)] absorbs light at a longer wavelength than [Fe(CN)).
• The colour arising from d-d transitions in [Fe(OH₂)61³ is less intense than
that arising from d-d transitions in [Fe(CN)s) ³.
Transcribed Image Text:(iv) In transition metal complexes such as those in part (a)(i), what determines the wavelength of light absorbed. (v) Using the answers to (a)(i) to (a)(iv), explain why: • [Fe(OH₂)] absorbs light at a longer wavelength than [Fe(CN)). • The colour arising from d-d transitions in [Fe(OH₂)61³ is less intense than that arising from d-d transitions in [Fe(CN)s) ³.
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