Make the structure based on the Blomstrand-Jorgensen Theory and Werner Theory also calculate the effective atomic number (NAE) and explain the function of the NAE a) Caz[Fe(CN),] b) K2[CrCO(CN);] c) [Ru(NH3)s(NO]CI

Q: Iron(III) forms octahedral complexes. Sketch the structures of all the distinct isomers of…

A: [Fe(en)2Cl2]+ has cis and trans both type of isomers. Where , "en" stands for ethylene di-amine…

Q: 1.43g sample of the complex [Co(NH3)4CO3]NO3 (MM=249 g/mol) was ignited in a crucible to convert all…

A: Previded amount of sample [Co(NH3)4CO3]NO3=1.43g Molar mass of [Co(NH3)4CO3]NO3=249g/mol Provided…

Q: Which of these ligands can participate in linkage isomerism:(a) SCN-; (b) S2O32-(thiosulfate); (c)…

A: Ligands having 2 donor atoms and which are capable of ligating through any of these donor atoms at a…

Q: By using valence bond theory and ligand field theory, prove [Fe(acac)3] is a paramagnetic high spin…

A: The valence bond theory provides information about the structure and magnetic properties of the…

Q: In [Cu(NH3)4]SO4.H2O, what is the type of the ligand, the coordination number, and the geometry?

A:

Q: a) Give an explaination on the stabilities of [V(CO)6J, [Ni(CO)4] and [Mn(CO)s] complexes. [Mn(CO)s]…

A: Introduction :  We have to tell stability of these complexes .

Q: Consider a second structure of the coordination sphere of Compared to the first structure, the third…

A:

Q: .a)Sketch structure, find oxidation state of Co and write name of coordination compound…

A: a) The structure of [Co(NH3)4(NO2)2]Cl The oxidation state of Co is found as follows, Therefore,…

Q: Crystal field splitting energy of the complex [CoBr (en), Cl, is A) 4 B) 5 - - 6. C) -A. 5 3 D) -2A,

A: Crystal field splitting in octahedral complex is into t2g and eg  t2g have 3 orbitals and eg have 2…

Q: <p>Many transition metal compounds are colored. How does crystal field theory account for…

A: The color of transition metal compounds is due to the absorbance of visible light. According to the…

Q: Consider the octahedral complexes of Co3+. Complete the following statements. The strong field…

A: The answer is given as follows

Q: The complexes of Fe^3+ have magnetic properties that depend onwhether the ligands are strong or weak…

A: The ligands are ranked on the basis of energy difference between the t2g and eg orbitals. When the…

Q: 26: d,e,f

A: Coordination number of central metal atom means to how many ligands it is bonded with how many bonds…

Q: When we consider the reaction of Fe3+ ion (SCN) with its ligand, by showing the ion-ligand bond in…

A: The reaction between Fe3+ and SCN- could be given as, Fe3+aq+SCN-aq→FeSCN2+ SCN- is a thiocyanate…

Q: 1) a,b,c,d

A: Coordination number is the total number of ligands that forms bond with the metal atom. (a)In…

Q: Many trace metal ions exist in the blood complexed with amino acids or small peptides. The anion of…

A: (a)

Q: Consider the coordination compound [Pt(NH3)4(OH)2]sO4 and identify ligands ? O a. O b. NH3 , SO4 O…

A: [Pt(NH3)4(OH)2]SO4

Q: Explain why [FeF6]³- is colorless whereas [COF6]³- is colored but exhibits only a single band in the…

A: The ligands which produces greater splitting in d orbitals are known as strong field ligands. The…

Q: What is the effective atomic number of the [Ir(CO)(PPh3)2Cl(NO)]+ complex?

A: Given Complex compound  [Ir(CO)(PPh3)2Cl(NO)]+ For calculation of effective atomic number (EAN) EAN…

Q: Why dp transition elements show variable oxidation states? In 3d series (Sc to Zn), which element…

A: Outer electronic configuration and Oxidation states  Sc  3d1 4s2                                + 2,…

Q: A complex of the type [M(AA)2X2]n+is known to be optically active. What does this indicate about the…

A: An optically active [M (AA) 2X2] n+ structure must be cis-octahedral in nature because, trans…

Q: 1) In accordance to Crystal Field Theory (CFT): Explain in details the difference between [Fe(CN),]*…

A:

Q: Using crystal field theory, draw an electron box energy level diagram for the valence d orbitals on…

A:

Q: Which of these ligands can participate in linkage isomerism:(a) NO2-; (b) SO2; (c) NO3-? Explain…

A: Linkage isomerism Suppose two complexes have the same molecular formula. But their structures differ…

Q: In platinum(IV) complexes, the octahedral crystal field splitting Do is relatively large. Is K2PtCl6…

A: Pt forms low spin complexes due to high energy gap between the t2g and eg orbitals.

Q: The values for lmax for complex A and B are 512 nm and 650 nm respectively.  A has the structure…

A: Given S.No. Complex  Imax 1 [Co(NH3)4CO3]NO3 512 nm 2 [Co(NH3)4Cl2]Cl.  650 nm Explain the…

Q: Why a diamagnetic metal complex once heated it posses a magnetic moment.

A: The diamagnetic complex is the one that tends to have paired electrons in the electronic…

Q: 1) In accordance to Crystal Field Theory (CFT): Explain in details the difference between [Fe(CN),]…

A:

Q: Indicate the likely coordination number of the metal in each of the following complexes: (a)…

A: Coordination number is the sum of ligand atoms attached to the central atom. That means the ligands…

Q: Please predict the number of unpaired electrons in [Ni(CN)4]² and [Fe(CN)6]*, explain your results…

A: In the [Ni(CN)4]4+ complex there is Ni2+ ion, whose electron distribution is as follows:

Q: Draw the geometrical isomers of complex [Co(en)2Cl2]+. (ii) On the basis of crystal field theory,…

A:

Q: Indicate the coordination number and the oxidation num- ber of the metal for each of the following…

A: Since we only answer up to 3 sub-parts, we’ll answer the first 3. Please resubmit the question and…

Q: Describe the steps involved in a water replacement reaction with a anion in octahedral complexes

A: Complex compounds are molecular compounds that do not lose their identity when dissolved in water or…

Q: For the following coordination compounds give their names via (a) Stock system, and (b)…

A: Since you have posted a question with multiple sub-parts, we will solve first three subparts for…

Q: Question 2a and 2b

A: Given complexes:

Q: Is a linkage isomer a type of constitutional isomer orstereoisomer? Explain

A: Linkage isomers are the coordination compounds with same metal and ligands but differ in the…

Q: 4. Using crystal field theory, prove [NiCla]²- is a tetrahedral paramagnetic complex.

A: The given complex is NiCl42-, has nickel metal as the central metal atom and the ligands are four…

Q: Name the following metal complexes or complex ions: formula name [Fe(OH), (en); ] [v(eN), (NH,).]…

A:

Q: a) Why the [Mn(H,O),]²* complex gives pale pink color where as MnO, gives intense color in water,…

A: “Since you have asked multip- le question, we will solve the first question for you. If you want any…

Q: Consider the coordination compound [Ni(C₂O4)2(H₂O)2] Cl2 and identify ligands a. C₂04-2, CI- -2 O b.…

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Q: The spectrochemical series: a. lists metals ions in order of their oxidation state. b. lists metals…

A: According to the crystal field theory the ligand atom acts as point negative change and the metal…

Q: Consider a second structure of the coordination sphere of Compared to the first structure, the…

A: Given isomers

Q: Question attached?

A: We are authorized to answer three subparts at a time, since you have not mentioned which part you…

Q: Explain why [Ni(NH;),] diamagnetic. is paramagnetic, while [Ni(CN), is

A: A complex become paramagnetic when it has electrons that are not paired. If all the electrons are…

Q: Name these coordination compounds. formula name Na, [CrCI, (H,0)] Br *[FeBr, (CO),]

A:

Q: When Werner's student Edith Humphrey first synthesized the complex complex salts of formula…

A: This is an example of Linkage isomerism of -NO2 ligand.  When a particular ligand is binding to a…

Q: A, B, C, and D are four different ligands, draw all possible structures of geometric isomers for…

A: In square - planar complex- All the four ligand are different i.e A, B, C, and DThe complex is Pt…

Q: Consider the coordination compound [Cr(H,O),Cl]CI and calculate the the coordination number of the…

A: Coordination number: Coordination number of a metal ion in a complex can be define as the number of…