Many metabolites are maintained at steady-state concentrations that are far from equilibrium. A comparison of Kéq and Q, the mass-action ratio, can determine whether a metabolic reaction is far from equilibrium. The equation for this equilibrium is, fructose 6-phosphate + ATP = fructose 1,6-bisphosphate + ADP Calculate Ke, for this reaction at T = 25.0 °C. AG' = -14.2 kJ/mol Calculate the mass-action ratio, Q, from the approximate physiological concentrations for rat heart tissue shown in the table. Metabolite Concentration (µM) Q = fructose 6-phosphate 84.0 fructose 1,6-bisphosphate 25.0 АТР 12,100 ADP 1,280 Select the true statements about the PFK-1 reaction. The PFK-1 reaction in heart tissue does not reach equilibrium. In heart tissue, the PFK-1 reaction will be driven toward product formation. In heart tissue, the PFK-1 products are more abundant than reactants. Under standard conditions, the PFK-1 reaction reaches equilibrium when the concentrations of all products and reactants are equal.
Many metabolites are maintained at steady-state concentrations that are far from equilibrium. A comparison of Kéq and Q, the mass-action ratio, can determine whether a metabolic reaction is far from equilibrium. The equation for this equilibrium is, fructose 6-phosphate + ATP = fructose 1,6-bisphosphate + ADP Calculate Ke, for this reaction at T = 25.0 °C. AG' = -14.2 kJ/mol Calculate the mass-action ratio, Q, from the approximate physiological concentrations for rat heart tissue shown in the table. Metabolite Concentration (µM) Q = fructose 6-phosphate 84.0 fructose 1,6-bisphosphate 25.0 АТР 12,100 ADP 1,280 Select the true statements about the PFK-1 reaction. The PFK-1 reaction in heart tissue does not reach equilibrium. In heart tissue, the PFK-1 reaction will be driven toward product formation. In heart tissue, the PFK-1 products are more abundant than reactants. Under standard conditions, the PFK-1 reaction reaches equilibrium when the concentrations of all products and reactants are equal.
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter16: Thermodynamics: Directionality Of Chemical Reactions
Section: Chapter Questions
Problem 83QRT: Another step in the metabolism of glucose, which occurs after the formation of glucose6-phosphate,...
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Many metabolites are maintained at steady‑state concentrations that are far from equilibrium. A comparison of ?′eq and ? , the mass‑action ratio, can determine whether a
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