Methane and hydrogen sulfide react to form hydrogen and carbon disulfide, like this: CH4(g)+2H,S(g)→ 4H2(g)+CS,(g) Use this chemical equation to answer the questions in the table below. Suppose 225. mmol of CH, and O None. 4 450. mmol of H, S are added to an O Some, but less than 225. mmol. empty flask. How much CH, will be O 225. mmol. 4 in the flask at equilibrium? O More than 225. mmol. Suppose 250. mmol of H, and O None. 62.5 mmol of CS, are added to an O Some, but less than 62.5 mmol. O 62.5 mmol. empty flask. How much CH, will be 4 in the flask at equilibrium? O More than 62.5 mmol.

Methane and hydrogen sulfide react to form hydrogen and carbon disulfide, like this: CH4(g)+2H,S(g)→ 4H2(g)+CS,(g) Use this chemical equation to answer the questions in the table below. Suppose 225. mmol of CH, and O None. 4 450. mmol of H, S are added to an O Some, but less than 225. mmol. empty flask. How much CH, will be O 225. mmol. 4 in the flask at equilibrium? O More than 225. mmol. Suppose 250. mmol of H, and O None. 62.5 mmol of CS, are added to an O Some, but less than 62.5 mmol. O 62.5 mmol. empty flask. How much CH, will be 4 in the flask at equilibrium? O More than 62.5 mmol.

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter4: Stoichiometry

Section: Chapter Questions

Problem 4.59PAE: 4.59 Aluminum dissolves in HCI according to the equation written below, whereas copper does not...

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On Easter Sunday, April 3, 1983, nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: 2HNO3(aq)+Na2CO3(aq)2NaNO3(aq)+H2O(l)+CO2(g) a. Calculate H for this reaction. Approximately 2.0 104 gal nitric acid was spilled. Assume that the acid was an aqueous solution containing 70.0% HNO3 by mass with a density of 1.42 glcm3. What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? (Hf for NaNO3(aq) = 467 kJ/mol) b. According to The Denver Post for April 4, 1983, authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of H, what was their major concern?
The pictures below show a molecular-scale view of a chemical reaction between H2 and CO to produce methanol, CH3OH The box on the left represents the reactants at the instant of mixing, and the box on the right shows what is left once the reaction has gone to completion. D Was there a limiting reactant in this reaction? If so, what was it? Write a balanced chemical equation for this reaction. As usual, your equation should use the smallest possible whole number coefficients for all substances.
4.90 Iron metal can be refined (rom the mineral hematite (Fe2O3). One way of converting the mineral to iron is to react it with carbon monoxide, as shown below: Fe2O3+3CO2Fe+3CO2 Because the hematite is obtained from various ores, it is usually not in a pure form. Suppose an iron manufacturer has 2.00 X 105 kg of ore available, and the ore is 93% Fe2O3 by mass. (There is no iron in the remaining 7% of the ore.) How many moles of Fe2O3are present in this ore? How many kg of pure iron could be obtained from this sample of ore? Assume that the process has a 100% yield and that excess CO is available.
A power plant is driven by the combustion of a complex fossil fuel having the formula C11H7S. Assume the air supply is composed of only N2 and O2 with a molar ratio of 3.76:1.00, and the N2 remains unreacted. In addition to the water produced, the fuels C is completely combusted to CO2 and its sulfur content is converted to SO2. In order to evaluate gases emitted at the exhaust stacks for environmental regulation purposes, the nitrogen supplied with the air must also be included in the balanced reactions. a Including the N2 supplied m the air, write a balanced combustion equation for the complex fuel assuming 100% stoichiometric combustion (i.e., when there is no excess oxygen in the products and the only C-containing product is CO2). Except in the case of N2, use only integer coefficients. b Including N2 supplied in the air, write a balanced combustion equation for the complex fuel assuming 120% stoichiometric combustion (i.e., when excess oxygen is present in the products and the only C-containing product is CO2). Except in the case of use only integer coefficients c Calculate the minimum mass (in kg) of air required to completely combust 1700 kg of C11H7S. d Calculate the air/fuel mass ratio, assuming 100% stoichiometric combustion. e Calculate the air/fuel mass ratio, assuming 120% stoichiometric combustion.
4.69 The pictures below show a molecular-scale view of a chemical reaction between H2 and CO to produce methanol, CH3OH. The box on the left represents the reactants at the instant of mixing, and the box on the right shows what is left once the reaction has gone to completion. Was there a limiting reactant in this reaction? If so, what was it? Write a balanced chemical equation for this reaction. As usual, your equation should use the smallest possible whole number coefficients for all substances.
4.59 Aluminum dissolves in HCI according to the equation written below, whereas copper does not react with HCl. 2Al( s )+6HCl( aq ) 2AlCl 3 ( aq )+ 3H 2 ( g ) A 35.0-g sample of a copper—aluminum alloy is dropped into 750 mL of 3.00 M HCl, and the reaction above proceeds as far as possible. If the ahoy contains 77.1% Al by mass, what mass of hydrogen gas would be produced?
Many cereals are made with high moisture content so that the cereal can be formed into various shapes before it is dried. A cereal product containing 58% H2O by mass is produced at the rate of 1000. kg/h. What mass of water must be evaporated per hour if the final product contains only 20.% water?
The space shuttle environmental control system handles excess CO2 (which the astronauts breathe out; it is 4.0% by mass of exhaled air) by reacting it with lithium hydroxide, LiOH, pellets to form lithium carbonate, Li2CO3, and water. If there are seven astronauts on board the shuttle, and each exhales 20. L of air pee minute, how long could clean air be generated if there were 25,000 g of LiOH pellets available for each shuttle mission? Assume the density of air is 0.0010 g/mL.
3.75 The following pictures show a molecular-scale view of a chemical reaction between the compounds AB2 and B2. (A atoms are shown in blue and B atoms in white). The box on the left represents the reactants at the instant of mixing, and the box on the right shows what is left once the reac- tion has gone to completion. Write a balanced chemical equation for this reaction. As usual, your equation should use the smallest possible whole number coefficients for all substances.
A 0.20 mol sample of magnesium burns in air to form 0.20 mol of solid MgO. What amount (moles) of oxygen (O2) is required for a complete reaction?
The carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.

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