Micrometers 2.5 100 9 10 7. 8 11 12 13 14 15 20 90 80 70 60 50 40 30 20 10 Compound D 4000 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 Wavenumber (cm-') Compound D SH 3H 2H IH IH 10 8. O ppm Chemical shift (8) Transmittance (%) 2.

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter5: Signals And Noise
Section: Chapter Questions
Problem 5.7QAP
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Following are IR and 1H-NMR spectra of compound D. The mass spectrum of compound D shows a molecular ion peak at m/z 136, a base peak at m/z 107, and other prominent peaks at m/z 118 and 59.

Q.) Propose structural formulas for ions in the mass spectrum at m/z 118, 107, and 59.

Micrometers
2.5
100
9 10
7.
8
11
12 13
14 15
20
90
80
70
60
50
40
30
20
10
Compound D
4000
3600
3200
2800
2400
2000
1800
1600
1400
1200
1000
800
600
400
Wavenumber (cm-')
Compound D
SH
3H
2H
IH
IH
10
8.
O ppm
Chemical shift (8)
Transmittance (%)
2.
Transcribed Image Text:Micrometers 2.5 100 9 10 7. 8 11 12 13 14 15 20 90 80 70 60 50 40 30 20 10 Compound D 4000 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 Wavenumber (cm-') Compound D SH 3H 2H IH IH 10 8. O ppm Chemical shift (8) Transmittance (%) 2.
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