Mixture I- (M) S208-2 (M) Initial Rate (M/s) 1 0.08 0.04 6.45 * 10 -4 2 0.04 0.04 3.54 * 10 -4 3 0.08 0.02 4.35 * 10 -4 PART B Mixture Temperature Rate Constant (k) 1 0.003390979993 4 0.003206155819

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter30: Kinetic Methods Of Analysis
Section: Chapter Questions
Problem 30.9QAP
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determine the rate constant k for mixtures 1, 4, 5 

rate = r = k[I-]^1 [S2O82-]^1

Mixture:                 Time (s):

1                                 61

4                                28

5                                85

PART A
Mixture
1- (М)
S208-2 (M)
Initial Rate (M/s)
1
0.08
0.04
6.45 * 10 -4
2
0.04
0.04
3.54 * 10 -4
3
0.08
0.02
4.35 * 10 -4
PART B
Temperature Rate Constant (k)
1 0.003390979993
Mixture
4 0.003206155819
5 0.003631082062
Transcribed Image Text:PART A Mixture 1- (М) S208-2 (M) Initial Rate (M/s) 1 0.08 0.04 6.45 * 10 -4 2 0.04 0.04 3.54 * 10 -4 3 0.08 0.02 4.35 * 10 -4 PART B Temperature Rate Constant (k) 1 0.003390979993 Mixture 4 0.003206155819 5 0.003631082062
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