NH4HS(s) NH3(g) + H₂S(g) ⇒ K = [NH3] [H₂S] K 1.2 x 10-4 What is the concentration of the NH3 when the system reaches equilibrium? [NH3] = [?] x 10¹¹ M C₂
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- The Handbook of Chemistry and Physics (http://openstaxcollege.org/l/16Handbook) gives solubilities of the following compounds in grams per 100 mL of water. Because these compounds are only slightly soluble, assume that the volume does not change on dissolution and calculate the solubility product for each. (a) BaSiF6, 0.026 g/100 mL (contains SiF62- ions) (b) Ce(IO3)4, 1.5102 g/100 mL (c) Gd2(SO4)3, 3.98 g/100 mL (d) (NH4)2PtBr6, 0.59 g/100 mL (contains PtBr62- ions)TOPIC: GRAVIMETRY SHOW THE SOLUTION The mercury in a 0.7152-g sample was precipitated with an excess of paraperiodic acid, H5IO6, according to the following reactions:5 Hg+2 + 2 H5IO6 ---> Hg5(IO6)2(s) + 10 H+The precipitate was filtered, washed free of precipitating agent, dried and found to weigh 0.3408-g. Calculate the percentage of Hg2Cl2 in the sample. Molar Masses: Hg5(IO6)2 = 1448.75 Hg2Cl2 = 472.09 Answer: 38.82% Hg2Cl2 An iron ore was analyzed by dissolving a 1.1324-g sample in concentrated HCl. The resulting solution was diluted with water, and the iron (III) was precipitated as the hydrous oxide Fe2O3·xH20 by the addition of NH3. After filtration and washing, the residue was ignited at a high temperature to give 0.5394 g of pure Fe2O3. Calculate (a) % Fe, and (b) % Fe3O4 in the sampleMolar Masses: Fe2O3 = 159.69 Fe = 55.847 Fe3O4 = 231.54 Answer: 33.32% Fe and 46.04% Fe3O4The hardness of water (hardness count) is usually expressed in parts per million (by mass) of CaCO3. What is the molar concentration of Ca2+ ions in a water sample with a hardness count of 175mg CaCO3il? How many milliliters of concentrated sulfuric acid, 94.0% (w/w), specific gravity of 1.831 are required to prepare 1 liter of a 0.100 M solution? The solubility-product constant for Ce(IO3)3 is 3.2x1010. What is the Ce3+ concentration in a solution prepared by mixing 50.0 ml of 0.0250 M Ce3.. with 50.00 ml of water?
- 1,5419 g of magnetite (Fe3O4) ore; in concentrated HCL to form a mixture of Fe + 2 and Fe+3it's unraveling. By adding HNO3 to it, all Fe+2 s are upgraded to Fe+3. And the addition of FE+3 s NH3,with Fe (OH)3, precipitating into. The sediment is weighed as 0.8525 g in the form of Fe2O3 after the necessary operations. Calculate the percentage of Fe3O4 in the sample.Ca2+ in a drinking water sample was analyzed by the following reactions below: Ca2+(aq) + C2O42-(aq) → CaC2O4 (s) → CaO(s) + CO(g)+ CO2(g) First an excess of C2O42- was added to 0.10 L of the Ca2+ water sample. Then CaC2O4 was precipitated, which was demcomposed into CaO with filtering and some heat. The CaO was measured to be 5.61 mg. What is the concentration of Ca2+ in the original water sample? The MW of CaO is 56.1 g/mol. 0.0100M 0.0010 M 1.00 M 0.100 M The partition coefficient (K) of methylamine (CH3NH2) is 4.50, preferring the organic layer over the aqueous layer in this extraction. The Ka of methylammonium (CH3NH3+) is 2.00 x 10-11. If 10 mL aqueous methylamine solution at pH 11.0 is extracted with 20.0 mL organic solvent, what is the fraction of solute remaining in the water (q)? HINT: methylamine is a weak base. 14.3% 10.0% 18.2% 81.8%Suppose 234.3 mg of PbCl2 was added to 16.0 mL of water in a flask, and the solution was allowed to reach equilibrium at 21.0 oC. Some solute remained at the bottom of the flask after equilibrium, and the solution was filtered to collect the remaining PbCl2, which had a mass of 91.6 mg . What is the solubility of PbCl2 (in g/L)? -Express the concentration in grams per liter to three significant figures.
- The solutbility constant for Ce(IO3)3 is 3.2x10^-10. What is the Ce3+ concentration in a solution prepared by mixing 50 mL of 0.0450 M Ce3+ with 50 mL of: A.) 0.0450 M IO3- ? B.) 0.0500 M IO3- ?1.1The Ksp of Ca3 (PO4 ) 2 is 1.3 × 10−26 . Estimate the solubility of this salt in units of g. L −1 . You must show any reaction equation(s) that you may think are necessary. 1.2 If a sample of solid Ca3(PO4)2 is stirred into exactly one litre of a 0.550M solution of Na3PO4, how will the solubility of the salt compare with the answer that you have obtained in question 1.1? Explain you answer in a short sentence.2KMnO4 (aq) +5H2C2O4 (aq) + 3H2SO4 (aq) > 10CO2 (g) + K2SO4 (aq) +2MnSO4 (aq) + 8H2O (l) 90ml of 0.0150 M KMnO4 solution is mixed with 30 ml of 0.095 M H2C2O4 solution in a medium where there is excess sulfuric acid. Assume 100% yield Calculate the concentration of the following ions or molecules in the final solution a) Mn2+ b) K+ c) MnO4- d)H2C2O4
- MnSO4•H2O is soluble in water at 25°C, with a solubility of 70.0 g per 1000 g of solution. A saturated solution of MnSO4•H2O has a density of 1.02 g mL-1. When MnSO4•H2O dissolves in water, it absorbs roughly 3.05 kJ/mol of energy. MnSO4•H2O = 169.03 g/mol; H2O = 18.02 g/mol; MW: MnSO4•H2O = 169.03 g/mol. Which of the following is TRUE about a 0.32 M solution of MnSO4•H2O in water? a. A 0.32 M solution contains 70.0 g MnSO4•H2O b. A 0.32 M solution of MnSO4•H2O is unsaturated c. A 0.32 M solution of MnSO4•H2O is supersaturated d. A 0.32 M solution of MnSO4•H2O is saturatedMnSO4•H2O is soluble in water at 25°C, with a solubility of 70.0 g per 1000 g of solution. A saturated solution of MnSO4•H2O has a density of 1.02 g mL-1. When MnSO4•H2O dissolves in water, it absorbs roughly 3.05 kJ/mol of energy. MnSO4•H2O = 169.03 g/mol; H2O = 18.02 g/mol; MW: MnSO4•H2O = 169.03 g/mol. What is the mole fraction of MnSO4•H2O in its saturated solution?In a lab, you diluted a sample of bleach to 1/10 concentration in a 250 vol. flask. Then quantitatively transferred into into a beaker and titrated it with a standard sodium thiosulfate solution with a molarity of 0.1215M. You repeated this 3 times. The data below is the amount of sodium thiosulfate that was titrated in the 3 runs. Calculate the molarity in each run of the diluted bleach and the concentration of undiluted bleach sample.