Nitrogen dioxide reacts bimolecularly in the gas phase to give NO2 + NO2 + ----> NO +NO + O2. The temperature dependence of the second-order rate constant for the rate law d[P]/dt = k[NO2]2 is given below. What are the Values of the steric factor P and the reactive cross-section for the reaction? Take σ = 0.60 nm2. T / K 600 700 800 1000 k / (cm3 mol−1 s−1) 4.6 ✕ 102 9.7 ✕ 103 1.3 ✕ 105 3.1 ✕ 106
Nitrogen dioxide reacts bimolecularly in the gas phase to give NO2 + NO2 + ----> NO +NO + O2. The temperature dependence of the second-order rate constant for the rate law d[P]/dt = k[NO2]2 is given below. What are the Values of the steric factor P and the reactive cross-section for the reaction? Take σ = 0.60 nm2. T / K 600 700 800 1000 k / (cm3 mol−1 s−1) 4.6 ✕ 102 9.7 ✕ 103 1.3 ✕ 105 3.1 ✕ 106
Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
Problem 86IL: The acid-catalyzed iodination of acetone CH3COCH3(aq) + I2(aq) CH3COCH2I(aq) + HI(aq) is a common...
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Nitrogen dioxide reacts bimolecularly in the gas phase to give
NO2 + NO2 + ----> NO +NO + O2.
The temperature dependence of the second-order rate constant for the rate law d[P]/dt = k[NO2]2 is given below. What are the Values of the steric factor P and the reactive cross-section for the reaction? Take σ = 0.60 nm2.
T / K | 600 | 700 | 800 | 1000 |
---|---|---|---|---|
k / (cm3 mol−1 s−1) | 4.6 ✕ 102 | 9.7 ✕ 103 | 1.3 ✕ 105 | 3.1 ✕ 106 |
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