Suppose that the typical diffusion coefficient for a reactant in aqueous solution at 25 °C is 5.2 × 10−9 m2 s−1. If the critical reaction distance is 0.4 nm, what value is expected for the second-order rate constant for the diffusion-controlled reaction?

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Answered: Suppose that the typical diffusion…

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter13: Chemical Kinetics

Section: Chapter Questions

Problem 13.42QE

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Suppose that the typical diffusion coefficient for a reactant in aqueous solution at 25 °C is 5.2 × 10⁻⁹ m² s⁻¹. If the critical reaction distance is 0.4 nm, what value is expected for the second-order rate constant for the diffusion-controlled reaction?

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