OCH 3 + CH3NH₂- a. Draw the structure of the tetrahedral intermediate INITIALLY-FORMED in the reaction shown. • You do not have to consider stereochemistry. . Do not include counter-ions, e.g., Na+, I, in your answer. . In cases where there is more than one answer, just draw one. b. Draw the structures of the organic products of the acyl transfer reaction. . You do not have to consider stereochemistry. • Draw the neutral form of the products; no charges. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. . Separate multiple products using the + sign from the drop-down menu. H₂O H₂SO4 NHCH₂CH3 a. Draw the structure of the tetrahedral intermediate INITIALLY-FORMED in the reaction shown. • You do not have to consider stereochemistry. . Do not include counter-ions, e.g., Na+, I, in your answer. . In cases where there is more than one answer, just draw one. b. Draw the structures of the organic products of the acyl transfer reaction. • You do not have to consider stereochemistry. • Draw the neutral form of the products; no charges. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter24: Catalytic Carbon-carbon Bond Formation
Section: Chapter Questions
Problem 24.39P: E. J. Coreys 1964 total synthesis of -caryophyllene (essence of cloves) solves a number of problems...
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3
OCH3 + CH3NH₂-
a. Draw the structure of the tetrahedral intermediate INITIALLY-FORMED in the reaction
shown.
• You do not have to consider stereochemistry.
. Do not include counter-ions, e.g., Na+, I, in your answer.
. In cases where there is more than one answer, just draw one.
b. Draw the structures of the organic products of the acyl transfer reaction.
. You do not have to consider stereochemistry.
• Draw the neutral form of the products; no charges.
• Draw one structure per sketcher. Add additional sketchers using the drop-down
menu in the bottom right corner.
• Separate multiple products using the + sign from the drop-down menu.
H₂O
H₂SO4
NHCH₂CH3
a. Draw the structure of the tetrahedral intermediate INITIALLY-FORMED in the reaction
shown.
• You do not have to consider stereochemistry.
. Do not include counter-ions, e.g., Na+, I, in your answer.
. In cases where there is more than one answer, just draw one.
b. Draw the structures of the organic products of the acyl transfer reaction.
• You do not have to consider stereochemistry.
• Draw the neutral form of the products; no charges.
• Draw one structure per sketcher. Add additional sketchers using the drop-down
menu in the bottom right corner.
• Separate multiple products using the + sign from the drop-down menu.
Transcribed Image Text:3 OCH3 + CH3NH₂- a. Draw the structure of the tetrahedral intermediate INITIALLY-FORMED in the reaction shown. • You do not have to consider stereochemistry. . Do not include counter-ions, e.g., Na+, I, in your answer. . In cases where there is more than one answer, just draw one. b. Draw the structures of the organic products of the acyl transfer reaction. . You do not have to consider stereochemistry. • Draw the neutral form of the products; no charges. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. H₂O H₂SO4 NHCH₂CH3 a. Draw the structure of the tetrahedral intermediate INITIALLY-FORMED in the reaction shown. • You do not have to consider stereochemistry. . Do not include counter-ions, e.g., Na+, I, in your answer. . In cases where there is more than one answer, just draw one. b. Draw the structures of the organic products of the acyl transfer reaction. • You do not have to consider stereochemistry. • Draw the neutral form of the products; no charges. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu.
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