Boost4:24 PMO 99%Doneeducation.wiley.com AA4 SolubilityOf the given compounds, which is moresoluble in water?Lö:H2C-H-CH2H2Č.H2O both are equally solubleHintSave for Later

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EBK A SMALL SCALE APPROACH TO ORGANIC L

4th Edition

ISBN:9781305446021

Author:Lampman

Publisher:Lampman

Chapter79: Solubility

Section: Chapter Questions

Problem 4P

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The Henry's law constant for the solubility of argon gas in water is 1.0103M/atm at 30C. (a) Express the constant in M/mm Hg. (b) If the partial pressure of argon gas at 30C is 693 mm Hg, what is the concentration (in M) of the dissolved argon gas at 30C? (c) How many grams of argon gas can be dissolved in 29 L of water at 693 mm Hg and 30C? (Ignore the partial pressure of water.)
Graph Table 14.10 shows solubility data that was collectedin an experiment. Plot a graph of the molarity ofKI versus temperature. What is the solubility of KI at55°C?
Supersaturated solutions of most solids in water are prepared by cooling saturated solutions. Supersaturated solutions of most gases in water are prepared by heating saturated solutions. Explain the reasons for the difference in the two procedures.
Air contains 78% nitrogen. At 25C, Henry's law constant for nitrogen is 6.8104M/atm, while at 37C, it is 6.2104M/atm. (a) How many milligrams of the nitrogen in the air will dissolve in 3.0 L of water at 25C? The air in the head space above the water has a pressure of 1.38 atm. (b) How many milligrams of the nitrogen in the air will dissolve in 3.0 L of water at 37C? The air in the head space above the water has a pressure of 1.38 atm. (c) How much more nitrogen is dissolved at the lower temperature in mass percent?
A gaseous solute dissolves in water. The solution process has H=15 kJ. Its solubility at 22C and 6.00 atm is 0.0300 M. Would you expect the solubility to be greater or less at (a) 22C and 1 atm? (a) 18C and 6 atm? (a) 15C and 10 atm? (a) 35C and 3 atm?
Consider two solutions at a certain temperature. Solution X has a nonelectrolyte as a solute and an osmotic pressure of 1.8 atm. Solution Y also has a nonelectrolyte as a solute and an osmotic pressure of 4.2 atm. What is the osmotic pressure of a solution made up of equal volumes of solutions X and Y at the same temperature? Assume that the volumes are additive.
The Henry's law constant for the solubility of helium gas in water is 3.8104M/atm at 25C. (a) Express the constant for the solubility of helium gas in M/mm Hg. (b) If the partial pressure of He at 25C is 293 mm Hg, what is the concentration of dissolved He in mol/L at 25C? (c) What volume of helium gas can be dissolved in 10.00 L of water at 293 mm Hg and 25C? (Ignore the partial pressure of water.)
6-53 Dioxin is considered to be poisonous in concentrations above 2 ppb. If a lake containing L has been contaminated by 0.1 g of dioxin, did the concentration reach a dangerous level?
Suggest an explanation for the observations that ethanol, C2H5OH, is completely miscible with water and that ethanethiol, C2H5SH, is soluble only to the extent of 1.5 g per 100 mL of water.
The freezing point of 0.10 M KHSO3 is -0.38C. Which of the following equations best represents what happens when KHSO3 dissolves in water? (a) KHSO3(s)KHSO3(aq) (b) KHSO3(s) K+(aq)+HSO3(aq) (c) KHSO3(s) K+(aq)+SO32(aq)+ H+(aq)
Using Figure 3.1, determine a. the number of grams of CuSO45H2O that will dissolve in 100g of H2O at 100C. gCuSO45H2O b. the number of grams of water required to dissolve 4.0g of CuSO45H2O at 100C. Hint: your answer to Problem 1a gives you the needed conversion factor for g CuSO45H2O to gH2O. gH2O c. the number of grams of water required to dissolve 18gKNO3 at 100C. gH2O d. the number of grams of water required to dissolve a mixture containing 18gKNO3 and 4.0g CuSO45H2O, assuming that the solubility of one substance is not affected by the presence of another. gH2O
You make a saturated solution of NaCl at 25 C. No solid is present in the beaker holding the solution. What can be done to increase the amount of dissolved NaCl in this solution? (See Figure 13.11.) (a) Add more solid NaCl. (b) Raise the temperature of the solution. (c) Raise the temperature of the solution, and add some NaCl. (d) Lower the temperature of the solution, and add some NaCl. Figure 13.11 The temperature dependence of the solubility of some ionic compounds in wafer. The solubility of most ionic compounds increases with increasing temperature This is illustrated using NH4CI (ports b and c).

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Of the given compounds, which is more soluble in water? Lö: H2C- H-Ć- CH2 H2 || O both are equally soluble |