3. Predict/Draw the structures of the products.OMeCHOPPh3opdOMe10 mol% Pd(PPH3)4NaOHSn"Bu310 mol% Pd(PPH3)4, NaOAcNaOHOMeGrubbs cat IICH₂l2, Zn(Hg)Br10 mol% PdCl₂(PPH3)220 mol% PCy3, DIPEACHBr3, NaOH

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OMe CHO + PPh3 NaOH CH₂l2, Zn(Hg) Br 10 mol% PdCl₂(PPH3)2 20 mol% PCy3, DIPEA

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

ChapterL2: Mass Spectrometry

Section: Chapter Questions

Problem 20CTQ

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Concept explainers

Mole Concept

Mole concept is a method to determine the amount of any substance that consists of some elemental particles using a grouping unit called ‘mole’. The mole concept enables one to handle the large amount of small elementary particles. The mole concept can be used in many calculations related to mole calculation, molar amount, mole ratio, and so on, which are significant in chemistry.

Question

3. Predict/Draw the structures of the products.
OMe
CHO
PPh3
opd
OMe
10 mol% Pd(PPH3)4
NaOH
Sn"Bu3
10 mol% Pd(PPH3)4, NaOAc
NaOH
OMe
Grubbs cat II
CH₂l2, Zn(Hg)
Br
10 mol% PdCl₂(PPH3)2
20 mol% PCy3, DIPEA
CHBr3, NaOH

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