оо || || HÖCH,CH2CH2C-CH2CH2CH2ÖČH

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter4: Polar Bonds, Polar Reactions
Section: Chapter Questions
Problem 30CTQ: According to the conventions above, what is the sign ( + or ) of the P.E. change (H) for Rxn 3?
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Hydrocarbon A, C10H14, has a UV absorption maximum at 236 nm and gives hydrocarbon B, C10H18, on catalytic hydrogenation. A reacts with maleic anhydride to yield a Diels-Alder adduct. Ozonolysis of A followed by zinc/acetic acid treatment yields the following diketo dialdehyde:

Propose a structure for hydrocarbon A

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||
HCH,CH2CH2Č-CCH,CH2CH,CH
Transcribed Image Text:о || HCH,CH2CH2Č-CCH,CH2CH,CH
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A structure for hydrocarbon C10H14 has to be proposed.

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