Organohalides are treated with lithium metal to yield an organolithium, which is in turn treated with copper(I) iodide to yield the corresponding Gilman reagent. Li Cul RX RLi R2CULI Decide what lithium diorganocopper (Gilman) reagent is needed to prepare 1- methylcyclohexene from 1-bromocyclohexene.

Organohalides are treated with lithium metal to yield an organolithium, which is in turn treated with copper(I) iodide to yield the corresponding Gilman reagent. Li Cul RX RLi R2CULI Decide what lithium diorganocopper (Gilman) reagent is needed to prepare 1- methylcyclohexene from 1-bromocyclohexene.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter19: Aldehydes And Ketones: Nucleophilic Addition Reactions

Section19.13: Conjugate Nucleophilic Addition To A,b-unsaturated Aldehydes And Ketones

Problem 22P: How might conjugate addition reactions of lithium diorganocopper reagents be used to synthesize the...

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