Answered: P3.10 Derive the following expression…

P3.10 Derive the following expression for calculating the isothermal change in the constant volume heat capacity: (aCv/av)T = T(0²P/ƏT²)v.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter2: The First Law Of Thermodynamics

Section: Chapter Questions

Problem 2.38E

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P3.10 Derive the following expression for calculating the
isothermal change in the constant volume heat capacity:
(aCv/av)T = T(0²P/ƏT²)v.

Expert Solution

Step 1

An isothermal process occurs in systems that have some means of regulating the temperature. This process occurs in systems ranging from highly structured machines to living cells. A few examples of an isothermal process are given below.

Changes in state or phase changes of different liquids through the process of melting and evaporation are examples of the isothermal process.
One of the examples of the industrial application of the isothermal process is the Carnot engine. In this engine, some parts of the cycles are carried out isothermally.

Detail handwritten expression mentioned in step 2

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