Part 3 out of 3 Grignard reaction: 4I CH,CHO MgBr edit structure Draw the intermediate product formed above and select the correct reagent for D. O H,SO, O H,0 O PCC O H2, Pd-C
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- What is the major product of the reaction of 1 mol of propyne with each of the following reagents? a. HBr (1 mol) e. aqueous H2SO4, HgSO4 h. H2/Lindlar catalyst b. HBr (2 mol) f. R2BH in THF followed by i. sodium amide c. Br2 (1 mol)/CH2Cl2 H2O2/HO-/H2O j. the product of part i followed by d. Br2 (2 mol)/CH2Cl2 g. excess H2, Pd/C 1-chloropropaneWhat are the correct reagents for this reaction? A.) NaBH4 and then H3O+ B.) LiAlH4/ether and then H3O+ C.) H2 with Pt/C D.) all of the aboveChoose the best reagents from the list provided below for carrying out the following conversion. Match the reagent with the step number. HCl (aq), Zn(Hg) Br2, FeBr3 Na/NH3, -33 degrees C NBS, light KMnO4, H3O+ Mg metal, ether KOH, EtOH, heat
- 1. What type of reaction is occuring in step 3? (halogenation, hydrohalogenation, reduction, keto–enol tautomerism, dehydrohalogenation, acid-catalyzed hydration, base-catalyzed hydration) 2. Which reagent is necessary for step 3? (Br2, HBr, H2/Pt, NaNH2, H20/H2SO4/HgSO4)In each reaction box, place the best reagent and conditions from the list below. 3-Hexanone should be the exclusive final product. (A reagent may be used more than once.)Choose the best reagents from the list provided below for carrying out the following conversion. Match the reagent with the step number. HCl (aq), Zn(Hg) KMnO4, H3O+ CH3Cl, AlCl3 HNO3, H2SO4 Cl2, FeCl3 fuming sulfuric acid
- 1. (a) Oxidation of 1-butanol with PCC will produce which of the following? 2-chlorobutanal butanone butanoic acid butanal (b) Which synthetic route is the best way to prepare ethyl isopropyl ether? CH3CH2OH + (CH3)2CHOH + H2SO4, 140 oC CH3CH2ONa + (CH3)2CHOH CH3CH2ONa + (CH3)2CHBr (CH3)2CHONa + CH3CH2Br1. (a) Oxidation of 1-butanol with PCC will produce which of the following? 2-chlorobutanal butanone butanoic acid butanal (b) Which synthetic route is the best way to prepare ethyl isopropyl ether? CH3CH2OH + (CH3)2CHOH + H2SO4, 140 oC CH3CH2ONa + (CH3)2CHOH CH3CH2ONa + (CH3)2CHBr (CH3)2CHONa + CH3CH2Br (c) The Williamson ether synthesis involves nucleophilic substitution involving an alkyl halide and an alcohol. (True or False)Provide a retrosynthesis (with complete reaction conditions) of the followingcompound from alkyl halides containing 6 carbons or less. The starting materials may be any type of alkyl halide (primary, secondary, or tertiary). You may use any other reagents you find necessary.