Pd(PPhah Pd(PPhyh 1. PPh, P-Pd-P H P-Pd-Si-H H. P-Pd- -Si-H Ppd-Si-H |Y Oxidative Addition Ligand Insertion Oxidative Ligand Insertion Reductive Elimination Reductive Lewis Base Association Lewis Base Association Oxidative Addition Oxidative A B Addition Elimination Reductive Elimination Reductive Ligand Insertion Lewis Base Association D Lewis Base Ligand Insertion Association Lewis Base Association Elimination Ligand Insertion Addition Oxidative Addition Reductive Elimination

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter14: Mass Spectrometry
Section: Chapter Questions
Problem 14.37P
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Question

The Palladium complex shown in the reaction scheme below will catalyze the addition of SiH4 to an alkene.  Identify the reaction types. 

A. B. C. .D. E.?

H
Pd(PPhah
H.
Pd(PPH33
1- PPhy
H
P-Pd-P
H
P-Pd-si-H
P-Pd-
X
H
P-Pd-Si-H
Y
Ligand Insertion Reductive
Elimination
Reductive
A
Lewis Base
Oxidative
Association
Lewis Base
Addition
Ligand Insertion
B
Oxidative
Association
Oxidative
Addition
Ligand Insertion Lewis Base
Elimination
Reductive
Addition
Oxidative
Association
Elimination
Reductive
D
Lewis Base
Association
Ligand Insertion
Addition
Elimination
Oxidative
Ligand Insertion
Lewis Base
Association
Reductive
Addition
Elimination
Transcribed Image Text:H Pd(PPhah H. Pd(PPH33 1- PPhy H P-Pd-P H P-Pd-si-H P-Pd- X H P-Pd-Si-H Y Ligand Insertion Reductive Elimination Reductive A Lewis Base Oxidative Association Lewis Base Addition Ligand Insertion B Oxidative Association Oxidative Addition Ligand Insertion Lewis Base Elimination Reductive Addition Oxidative Association Elimination Reductive D Lewis Base Association Ligand Insertion Addition Elimination Oxidative Ligand Insertion Lewis Base Association Reductive Addition Elimination
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