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Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter10: Effect Of Electrolytes On Chemical Equilibria
Section: Chapter Questions
Problem 10.8QAP
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a) AICI3 has a solubility constant, Ks of 2.911 × 103. An aqueous saturated
solution of AICI3 has a molality of 3.465 mol kg-1. Calculate the mean
activity coefficient for this solution.
b) A weak aqueous solution of SrBr2 is prepared at 25.0 °C by dissolving
53.3 umol in 40.0 g of water. Determine the mean activity coefficient for
this solution, justifying your choice of method.
c) Given the standard reduction potentials for two ions of element X
X+ + e- → X
E® = 0.378 V
X2+ + 2e- → X
E° = 1.212 V
calculate the standard reduction potential for the half reaction
X2+ + e- → X*
Transcribed Image Text:a) AICI3 has a solubility constant, Ks of 2.911 × 103. An aqueous saturated solution of AICI3 has a molality of 3.465 mol kg-1. Calculate the mean activity coefficient for this solution. b) A weak aqueous solution of SrBr2 is prepared at 25.0 °C by dissolving 53.3 umol in 40.0 g of water. Determine the mean activity coefficient for this solution, justifying your choice of method. c) Given the standard reduction potentials for two ions of element X X+ + e- → X E® = 0.378 V X2+ + 2e- → X E° = 1.212 V calculate the standard reduction potential for the half reaction X2+ + e- → X*
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