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- The molar conductivities at infinite dilution of aqueous solutions of NH4Cl, NaCl, and NaOH are, respectively, 130, 108.6, and 216.5 S cm2 mol-1 at 18°C. The specific conductivity of a 0.01 M solution of ammonia at the same temperature is 9.6 x 10-5 [S cm-1] and the ion product of water is 0.59 x 1014. Determine: • The concentration of NH4+ ions in the ammonia solution. • The pH of the ammonia solution.The mean activity coefficient of a 0.2 b Mg (NO3)2 solution is 0.13 at 25oC. Calculate the mean molality, the mean ionic activity and the activity of the compound.Estimate the mean ionic activity coefficient of NaCl in a solution that is 0.020 mol kg−1 NaCl(aq) and 0.035 mol kg−1 Ca(NO3)2(aq) at 25 °C.
- Calculate the % relative error in solubility by using concentrations instead of activitiesfor Fe(OH)2 in 0.0500 M KNO3 (give the source for thermodynamic solubility).Estimate the mean ionic activity coefficient of CaCl2 in a solution that is 0.010 mol kg−1 CaCl2(aq) and 0.030 mol kg−1 NaF(aq) at 25 °C.Estimate the mean ionic activity coefficient and activity of a solution that is 0.015 mol kg-1 MgF2(aq) and 0.025 mol kg-1 NaCI(aq).
- The mean activity coefficient of a 0.010 m H2SO4 solution is 0.544. What is its mean activity?Consider a saturated solution of barium iodate in 0.025 M BaCl2. For the salt: Ba(IO3)2(s) ⇌ Ba2+ + 2IO3- Ksp = 1.57 \times× 10-9 at 25 deg C What is the activity coefficient of Ba2+? Consider a saturated solution of barium iodate in 0.025 M BaCl2. For the salt: Ba(IO3)2(s) ⇌ Ba2+ + 2IO3- Ksp = 1.57 × 10-9 at 25 deg C What is the activity coefficient of Ba2+?. 0.439 0.364 0.276 0.405As part of the analysis of water samples, the hardness of water is commonly measured and calculated. It is commonly expressed in ppm by mass (parts per million) of CaCO3. Parts per million is also equivalent to milligrams of CACO3 per liter of water. In a sample taken by an environmentalist, he was able to observe a hardness count of 205 mg CacO3/L. Given this hardness count of the sample, what is the molar concentration of Ca2+ ions in the water sample?
- Calculate the solubility of the BaSO4 solid in 0.0167 M Ba (NO3) 2 solution, taking into account the activity. (Ksp for BaSO4, activity coefficients for 1.1x10^-10 Ba^2+ and SO4^2- ions are 0.46 and 0.44, respectively)Use the expression of the activity coefficient to calculate the coefficient of activity of cobalt in the equilibrium solubility of Co (OH) 2 (Ksp = 1.3 x 10-15) in the presence of a solution containing 0.0333M NaCl. ions α: αCo 2+ = 0.45nm, αOH- = 0.30nm, -log γx = 0.51 zx2 √µ 1 + 3.3 αx√µ Select one:to. 0.51b. 0.91c. 0.75d. 0.83The mean activity coefficients of KCl in three dilute aqueous solutions at 25 °C are 0.927 (at 5.00 mmol kg−1), 0.902 (at 10.0 mmol kg−1), and 0.816 (at 50.0 mmol kg−1). Estimate the value of B in the Davies equation.