Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. 2. (CH3)2S Bra CH₂OH 1.03 2. DMS KMnO4, NaOH cold 19 18 17 16 15 HI mCPBA 1. OsO4 2. H₂O₂ CHCO3H (peroxyacid) FBA 550 14 Pd or Pt (catalyst) 20 2 12 11 10 HBr ROOR (peroxide) H₂O H₂SO4 HCI 1. BH₁.THF 2. H₂O2, NaOH Br2 H₂O BH, THF EIOH Br₂ Pd or Ni (catalyst) D₂ (deuterium) Br₂ O A B с D A B Br H Br C Br D H "Br H ***Br
Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. 2. (CH3)2S Bra CH₂OH 1.03 2. DMS KMnO4, NaOH cold 19 18 17 16 15 HI mCPBA 1. OsO4 2. H₂O₂ CHCO3H (peroxyacid) FBA 550 14 Pd or Pt (catalyst) 20 2 12 11 10 HBr ROOR (peroxide) H₂O H₂SO4 HCI 1. BH₁.THF 2. H₂O2, NaOH Br2 H₂O BH, THF EIOH Br₂ Pd or Ni (catalyst) D₂ (deuterium) Br₂ O A B с D A B Br H Br C Br D H "Br H ***Br
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter25: Enolate & Enol Nucleophiles
Section: Chapter Questions
Problem 15E
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