Polyethylene glycol 400 (PEG400) is a nonvolatile liquid polymer, which when mixed with water canbe used as a base for parenteral formulations. The designation “400” means that the molecular weightof PEG molecules is approximately 400 g/mol. Preparation with water (ΔHv = 40.7 kJ/mol) requires that the two be mixed at 56 oC, at which the equilibrium vapor pressure of pure water is 16.5 kPa.a. If 105 g of PEG400 are added to 500 g of water at 56 oC, what will the boiling temperature of the solution be?

Molality of solution is determined as follows,

Answered: Polyethylene glycol 400 (PEG400) is a…

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter12: Solutions

Section: Chapter Questions

Problem 12.87QE

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Polyethylene glycol 400 (PEG400) is a nonvolatile liquid polymer, which when mixed with water canbe used as a base for parenteral formulations. The designation “400” means that the molecular weightof PEG molecules is approximately 400 g/mol. Preparation with water (ΔHv = 40.7 kJ/mol) requires that the two be mixed at 56 oC, at which the equilibrium vapor pressure of pure water is 16.5 kPa.

a. If 105 g of PEG400 are added to 500 g of water at 56 oC, what will the boiling temperature of the solution be?

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