Pool of Mechanisms: CAR. SN1 only TAR. E1 only FAR. SN1 and E1 BAR. SN2 only JAR. E2 only WAR. SN2 and E2 Substrate: Reagent/Condition: KCN Choose... + Br CH3 Reagent/Condition: K* o-c-CH3 Substrate: `Br CH3 Choose... t-BUOK Substrate: Reagent/Condition: NH3 Choose... + Br

Pool of Mechanisms: CAR. SN1 only TAR. E1 only FAR. SN1 and E1 BAR. SN2 only JAR. E2 only WAR. SN2 and E2 Substrate: Reagent/Condition: KCN Choose... + Br CH3 Reagent/Condition: K* o-c-CH3 Substrate: `Br CH3 Choose... t-BUOK Substrate: Reagent/Condition: NH3 Choose... + Br

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter8: Addition Via Carbocation

Section: Chapter Questions

Problem 6CTQ

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Concept explainers

Designing a Synthesis

Organic synthesis is a branch of chemical synthesis that involves the planned construction of organic compounds/molecules from smaller units that possess functional groups. Friedrich Wöhler was the first scientist who designed the synthesis of an organic compound, urea from inorganic starting materials silver cyanate with ammonium chloride via a simple, one-step synthesis.

Question

Match each of the following sets of substrate and reagent/condition with the pool of mechanism they may possibly undergo.

Pool of Mechanisms:
CAR. SN1 only
TAR. E1 only
FAR. SN1 and E1
BAR. SN2 only
JAR. E2 only
WAR. SN2 and E2
Substrate:
Reagent/Condition: KCN
Choose... +
Br
CH3
Reagent/Condition: K* o-c-CH3
Substrate:
Br
CH3
Choose... +
t-BUOK
Substrate:
Reagent/Condition: NH3
Choose... +
Br

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