Potassium dichromate is used to titrate a sample containing an unknown percentage of iron (AW. 55.845 g/mol ). The sample is dissolved in H3PO4/H2SO4 mixture reduce all of the iron to Fe<* ions. The solution is then titrated with 0.01625 M K2Cr207, producing Fe* and Cr* ions in acidic solution. The titration requires 32.26 mL of K2Cr207 for 1.2765 g of the sample.

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter22: The Chemistry Of The Transistion Elements
Section22.7: Colors Of Coordination Compounds
Problem 3.3ACP
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Potassium dichromate is used to titrate a sample containing an unknown percentage of iron (AW. 55.845 g/mol ). The sample is dissolved in H3PO4/H2SO4 mixture to
reduce all of the iron to Fe2* ions. The solution is then titrated with 0.01625 M K2Cr207, producing Fes+
mL of K2Cr207 for 1.2765 g of the sample.
and Cro+ ions in acidic solution. The titration requires 32.26
6F22+ + Cr2072- + 14H* .
---> 6 Fe3+ + 2Cr3+
7H2O
+
Determine the percent iron in the sample.
13.76%
12.13%
15.48%
14.92%
Transcribed Image Text:Potassium dichromate is used to titrate a sample containing an unknown percentage of iron (AW. 55.845 g/mol ). The sample is dissolved in H3PO4/H2SO4 mixture to reduce all of the iron to Fe2* ions. The solution is then titrated with 0.01625 M K2Cr207, producing Fes+ mL of K2Cr207 for 1.2765 g of the sample. and Cro+ ions in acidic solution. The titration requires 32.26 6F22+ + Cr2072- + 14H* . ---> 6 Fe3+ + 2Cr3+ 7H2O + Determine the percent iron in the sample. 13.76% 12.13% 15.48% 14.92%
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