Predict the major product(s) for all of the 6 following chemical reactions. Indicate the stereochemistry where it is relevant. 6. I. I2 ? CuCl2 C. "СНз Ur goiwolldt odlo does ot ouibooouow adi wll Borhe -2 01okio-8-2 ii) 1. BH3 / THF 2. H,О2/"ОН OH iii) KMNO4 Н.О Cl CI bos ploseeioboi-n Ha iv) 1. Na NH2 C CH 2. H bns tolbs 1. OsO4 OH -? 2. NaHSO3/H20 он vi) НBr ? CPCH ether 4.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions
Section20.6: Sigmatropic Shifts
Problem 20.12P
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Predict the major product(s) for all of the 6 following chemical reactions. Indicate the stereochemistry
where it is relevant.
6.
I.
I2
?
CuCl2
C.
"СНз
Ur goiwolldt odlo does ot ouibooouow adi wll
Borhe
-2 01okio-8-2
ii)
1. BH3 / THF
2. H,О2/"ОН
OH
iii)
KMNO4
Н.О
Cl
CI
bos ploseeioboi-n
Ha
iv)
1. Na NH2
C CH
2. H
bns tolbs
1. OsO4
OH
-?
2. NaHSO3/H20
он
vi)
НBr
?
CPCH
ether
4.
Transcribed Image Text:Predict the major product(s) for all of the 6 following chemical reactions. Indicate the stereochemistry where it is relevant. 6. I. I2 ? CuCl2 C. "СНз Ur goiwolldt odlo does ot ouibooouow adi wll Borhe -2 01okio-8-2 ii) 1. BH3 / THF 2. H,О2/"ОН OH iii) KMNO4 Н.О Cl CI bos ploseeioboi-n Ha iv) 1. Na NH2 C CH 2. H bns tolbs 1. OsO4 OH -? 2. NaHSO3/H20 он vi) НBr ? CPCH ether 4.
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