Predict the product of the Diels-Alder reaction of this compound with cyclopentadiene. Draw your product in the window below. CI CH H₂C You do not have to consider stereochemistry. Potential bicyclic templates are provided in the starting points dropdown menu should you require them.

Predict the product of the Diels-Alder reaction of this compound with cyclopentadiene. Draw your product in the window below. CI CH H₂C You do not have to consider stereochemistry. Potential bicyclic templates are provided in the starting points dropdown menu should you require them.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter14: Conjugated Compounds And Ultraviolet Spectroscopy

Section14.SE: Something Extra

Problem 17VC: Show the product of the Dielsâ€“Alder reaction of the following diene with 3-buten-2-one, H2C =...

See similar textbooks

Related questions

Q: Which of the following aqueous solutions are good buffer systems? (Select all that apply.)…

A: The aqueous solutions given are 0.18 M hydrocyanic acid + 0.17 M sodium cyanide 0.27 M nitric acid…

Q: 102 for the reaction given below. H2(g) + F2(g) 2 HF(g) (a) Calculate the concentrations of all…

Q: A 0.10 M weak acid is titrated with a 0.10 M strong base. Plot the titration curves on the same…

Q: What would the resonance for this structure be?

A: Resonance structures: These are the groups of two or more Lewis Structures that together represent a…

Q: 0.178 mole sample of solid NaX is dissolved in 275 mL of water in an insulated container at 23.7°C…

A: The question is based on the concept of specific heat capacity. It is defined as the amount of heat…

Q: What mass of MgCO3 contains the same mass of oxygen as does 321 mg of MgCr2O7? mg

A: mass of MgCr2O7 = 312mg 1g = 1000 mg so mass of MgCr2O7 = 312mg x1g1000 mg= 0.312 g

Q: At 2.86 atm and 494 K, what volume of NO₂ gas forms from 59.66 g of O₂? 4 NH3(g) +70₂(g) → - 4NO₂(g)…

Q: state which ones are rotational Raman active and explain why (a) H2O (b) CO2 (c) NH3 (d) N2O…

A: Rotational Raman active molecules are those that have a polarizability that changes during rotation,…

Q: 9) Within a balloon, there are three types of gasses. You have 12.7 grams of gas #1 (N₂ gas), 9.7…

Q: Determine whether each change represents oxidation or reduction. Oxidation C6H₁2O6 to CO₂ C₂H₂O to…

A: Oxidation means increase of oxidation state. The loss of electrons or the removal hydrogens or the…

Q: A student prepared their sample for Trial 2. They added 2.30 mL of 0.002M KSCN, 5.16 mL of 0.002M…

A: A student prepared their sample for Trial 2. They added 2.30 mL of 0.002M KSCN, 5.16 mL of 0.002M…

Q: A solution is made by mixing 569 mL of water and 238 mL ethanol. What is the concentration of…

A: Given data :- Volume of water = 569 mL Volume of Ethanol = 238 mL To find Concentration of…

Q: Part A 0.100 M in HBr and 0.140 M in HCHO₂ (K₁ = 1.8 x 10-¹) Express your answer to two decimal…

Q: MISSED THIS? Watch KCV Limiting Beactant Theoretical Yield and Percent Yield WE Limiting Reactant…

Q: Write the formula of the conjugate base of the Brønsted-Lowry acid, H₂S

Q: Which of the following is a strong nucleophile in a protic solvent? Select answer from the options…

Q: How many grams of Fe(CH₂COO)2 are there in 201 grams of an aqueous solution that is 11.5% (w/w)…

A: For the Fe(CH3COO)2 [Iron(II) acetate] solution Mass of solution = 201 g Mass % of Fe(CH3COO)2…

Q: Which one of the equations below is an endothermic reaction? A) SrO (s) + CO2 (g) → SrCO3 (s)AH =…

A: The chemical reactions in which energy is require to proceed the reaction is known as endothermic…

Q: the laboratory you are given the task of separating Ca2+ and Ag+ ions in aqueous solution. For each…

A: Ca2+ (aq) + SO42- (aq) => CaSO4 (s) (precipitate is formed) 2 Ag+ (aq) + SO42- (aq) => Ag2SO4…

Q: Draw the organic product(s) formed when CH3CH₂CH₂OH is treated with each reagent. a. H₂SO4 d. HBr b.…

Q: Chemical Bonding How man electrons can be held in each of the three electron shells? 1. 2. 3. List…

A: In an atom, there are three types of fundamental particles. In the nucleus there are protons and…

Q: ← Draw the major product of this reaction. Ignore inorganic byproducts. x H₂O* Drawing O Problem 310…

Q: state which of the following molecules show a pure rational microwave absorption spectrum and…

A: The molecules that show a pure rotational microwave absorption spectrum are those that have a…

Q: CH3-CH2-CH2-CH2-CH2-O-CH2-CH2-CH2-CH3 0° -O-CH2-CH3 F OH

A: 3 parts of the question have been answered below. Ask other parts in another question please.…

Q: Ammonium perchlorate NH4ClO4 is the solid rocket fuel that was used by the U.S. Space Shuttle and…

Q: 1) For each of the reactions below, draw the whether the relative stereochemistry of syn or unknown.…

A: We know , HBr helps in hydrobromination of double bond and mCPBA helps in epoxidation across double…

Q: Describe the major function of a. Phosphorus in the bones b. Sodium in the extracellular fluid

A: This question asks for a detailed explanation of the major functions of three different minerals in…

Q: 8.8 There are three possible products in the reaction below. Study the 'H NMR spectrum on the next…

A: Identification of the organic compounds with NMR spectroscopy.

Q: Which of the following molecules is most basic? b C Select an answer and submit. For keyboard…

Q: Give the chemical symbol for the element with the ground-state electron configuration [Ar]4s²3d".…

Q: 11 8. When benzene is treated with Reagent(s) A followed by Reagent(s) B, Compound P (CaHCIO) is the…

Q: Write the basic equilibrium equation for (CH3)2NH. Be sure to include the proper phases for all…

A: Answer:- Equilibrium refers to a state where the rates of the forward and reverse reactions are…

Q: Determine [OH-] of a solution that is 0.260 M in HCO3-. (Ka1 for H2CO3 is 4.3x10-7.)

A: Given, Molarity of HCO3- = 0.260 M Ka1 of H2CO3 = 4.3 × 10-7

Q: See Figure 8-6. Which of the following statement(s) is/are FALSE about this reaction? 00 The process…

Q: Beaker 0.00200 M Fe(NO3)3, mL 0.00200 M NaSCN, mL total volume, mL 1 3.000 2.000 10.00 2…

A: Molarity is a method of expressing concentration of solution. we need to calculate concentration of…

Q: ning. TOUT SLUTC Will be based on the TUTTINCT OF Cunelmans minds the five on nel malenes. mere is…

A: “Since you have posted multiple questions, we will provide the solution only to the first question…

Q: The components of substances that are ______ separate when the substance is placed in water.…

A: Substances which are completely dissociated in aqueous solution are called ionic substances.

Q: The volume of water needed to dissolve 0.0651 grams of magnesium fluoride is ..... L. Assume no…

A: We need to find the volume of water needed to dissolve 0.0651g of MgF2

Q: At a certain temperature this reaction follows first-order kinetics with a rate constant of 1.57 s…

A: 2Cl2O5(g) ----> 2Cl2(g) + 5O2(g) Reaction follows first order kinetics. Rate constant (k) = 1.57…

Q: X₂ x H H H₂O H₂O x :CI:O H HH Select to Add Arrows H 0: H₂O Select to Add Arrows

A: We have to draw the curved arrows for the every steps.

Q: 8 HO-CH₂CH2-OH H* + H₂O

A: Organic reactions are those in which organic reactant react to form organic products. In the given…

Q: he pH of a 0.35 M solution of hydrocyanic acid (HCN) is measured to be 4.83. Calculate the acid…

A: pH = 4.83 Concentration of HCN (c) = 0.35M Ka = ?

Q: Consider the weak base, B -, in water as shown in the reaction below. The [B -] initially is 0.460 M…

A: [B-] initially (c) = 0.460M Kb = 2.04×10-6 pH of solution = ?

Q: A monatomic ion with a charge of +2 has an electronic configuration of 1s²2s²2p…

A: Question is based on the concept of atomic structure. We have been given electronic configuration.…

Q: 2. There are 36.7 grams of ammonia gas trapped in a non- deformable container. Calculate the volume…

A: Answer-2 STP means standard temperature and pressure where pressure is equal to 1 atm and…

Q: Complete the mechanism for the given reaction by adding the missing curved arrows. Step 1: Add…

A: We have to draw the curved arrow to complete mechanism.

Q: Figuie 8-2 т Н+ 1 А. ET с. ер H 30+ ли rxn prog гхи prog он 2 P. В. ET EI 4 H₂O: Inn гхи prog л ГХИ…

A: Proton transfer :- The process of a chemical reaction in which a species is protonated and other…

Q: What would the resonance for this structure be?

A: Resonance structures: These are group of two or more structures that collectively represent all the…

Q: What is the heat capacity of a bomb calorimeter if the combustion of 2.888 mmol of salicylic acid…

A: To solve this problem we have to calculate the heat capacity of bomb calorimeter .

Q: N(CH3)2 H₂O, H* S + H-N(CH3)2

A: From reactant to product conversion an enamine is converted into keton in the presence of H3O+, H2O…

Concept explainers

UV Visible Spectroscopy

Spectroscopy refers to the absorption or emission of light or other radiations by matter. When a substance or chemical absorbs light or radiation, they reach an excited state followed by de-excitation or emission of the light or radiation forming distinct spectra. UV-visible spectroscopy or ultraviolet-visible refers to the absorption and emission in the ultraviolet and visible regions of the electromagnetic spectrum.

Question

Jj.25.

Predict the product of the Diels-Alder reaction of this compound with cyclopentadiene. Draw your product in the window below.
CI
CH
H₂C
You do not have to consider stereochemistry.
Potential bicyclic templates are provided in the == starting points dropdown menu should you require them.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1: Diels-Alder reaction

VIEW

Step 2: Given reaction

VIEW

Step 3: Answer

VIEW

Solution

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 4 steps with 3 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Although the Dielsâ€“Alder reaction generally occurs between an electronrich diene and an electron-deficient dienophile, it is also possible to have inverse-demand Dielsâ€“Alder reactions between suitable electrondeficient conjugated double bonds and electron-rich alkenes. These reactions are particularly useful because they allow for the incorporation of heteroatoms into the new six-membered ring. Predict the products of each inverse-demand Dielsâ€“Alder reaction below. Be sure your products reflect the correct stereochemistry. If more than one regioisomer is possible, draw both.
A2 What is the inverse electron demand Diels–Alder reaction? Please pick a pair of a diene and a dienophile from the following dienes and dienophile that will undergo this type of reaction. Please show how this reaction works using Frontier Molecular Orbitals. What is the reaction product?
Exp3: Diels-Alder reaction Why does cyclopentadiene regularly form a dimer? How to break the dimer into monomers? Does the diene in this reaction act as the nucleophile or the electrophile? Is the maleic anhydride a nucleophile or an electrophile in this reaction? Explain your reasoning.
When the allylic alkyl bromide shown below is heated in ethanol solvent, the major elimination product isolated is the diene shown below. A) Propose a mechanism to account for this overall transformation. Use normal curved arrows to show movement of electron pairs and be sure to draw structures for all important reaction intermediates. If an intermediate is a resonance hybrid, draw all important contributing resonance structures. B) The same alkyl bromide shown above also yields several substitution products when subjected the reaction conditions described above. Draw the structure of the major substitution product that would be isolated in the box on the product side of the reaction arrow. The second picture is for the B part of the question
What is the product (include the stereochemistry) of the 6 pi electron electrocyclic reaction below, use the appropriate Woodward-Hoffman rule.
Diels–Alder reaction of a monosubstituted diene (such as CH2=CH–CH=CHOCH3) with a monosubstituted dienophile (such as CH2=CHCHO)gives a mixture of products, but the 1,2-disubstituted product oftenpredominates. Draw the resonance hybrid for each reactant, and use thecharge distribution of the hybrids to explain why the 1,2-disubstitutedproduct is the major product.
Assign the stereochemical configuration (E or Z) for the alkene below. Show your work, indicating clearly which groups are assigned high priority (e.g., through assigning the groups numbers, circling only the high priority groups, or labeling groups as high or low).
Rank the following dienes in their rate of reaction with the same dienophile in a Diels-Alder reaction. For example, 1 = fastest or most reactive diene, 4 = slowest or least reactive diene.
Give 3 examples of a reaction mechanism of E1 that follows Zaitsev's rule.
The 3D image below is that of an allylic carbocation intermediate formed by the protonation of a conjugated diene with HBr. Draw structural formulas for the final reaction products.
Diels—Alder reaction of a monosubstituted diene (such as CH2 = CH – CH = CHOCH3) with a monosubstituted dienophile (such as CH2 = CHCHO) gives a mixture of products, but the 1,2-disubstituted product often predominates. Draw the resonance hybrid for each reactant and use the charge distribution of the hybrids to explain why the 1,2-disubstituted product is the major product.
Uemura and coworkers studied a time dependent Diels-Alder reaction which first formed the endo product as the major organic product and with time produced the exo product (J. Org. Chem. 2018, 83, 9300−9304). Show the endo and exo product for the reaction below. Which is the thermodynamic product and which is the kinetic product? Explain your reasoning.