Prepare this aqueous mixture: 300 mL 0.1 M HNO2 & 100 mL 0.1 M PO4 3- a. HNO2 is in excess & PO43- is polyprotic. Give all acid-base reactions that can occur when excess HNO2 is mixed w/ PO4 3-. (3 reactions) b. Calculate Keq for the individual reactions for (a). For each, are reactants or products favored at equilibrium?
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- A suitable target for the titration is 30.0 cm3 of 0.025 moldm-3 Br2(aq) Justify why a much smaller target titre would not be appropriate Calculate the amount in moles of bromine in the target titer Justification? calculate a suitable massof alive oil to transfer to the volumetric flask using your answer to of above question and the structure of Y Assume that the olive oil contains 85/- of Y by mass (If you were unable to calculate the amount of bromine in the target titer,you should assume it is 6.25×10^-8 mol .this in not the correct amount)The following text may be found at the ThermoFisher website: "PBS (phosphate buffered saline) is a pH-adjusted blend of ultrapure-grade phosphate buffers and saline solutions which, when diluted to a 1X working concentration, contains 137 mM NaCl, 2.7 mM KCl, 8 mM Na2HPO4, and 2 mM KH2PO4. Each 10X PBS solution is ready to use upon dilution to the desired concentration." This means that the product that you purchase has a concentration 10 times the concentration at which it is used. 1. Look up the pKa values for phosphoric acid and list them as a part of your response. 2. Based on the description of the contents of the PBS buffer, calculate the pH of the 1X solution. 3. Assume that you wish to use a pH = 7.00 buffer. If your answer to 2 was more acidic than pH 7.00, calculate how much 1.00 M NaOH you would need to add to get to pH = 7.00. If your answer to 2 was more basic than pH 7.00, calculate how much 1.00 M HCl you would need to add to get to pH = 7.00.A 0.3012g sample of an unknown monoprotic acid requires 24.13mL of 0.0944MNaOH for neutralization to a phenolphthalein end point. There are 0.32mL of 0.0997MHCl used for back titration. a. How many moles of OH are used? How many moles of H+ from HCl? _______moles OH ________moles H+ b. How many moles of H+ are there in the solid acid? Use Eq.5. ____________ moles H+ in solid c. What is the molar mass of the unknown acid? Use Eq.4. ____________ g/mol
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