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- Using a simple infinite barrier approximation, calculate the “effective bandgap” of a 10 nm GaAs/AlGaAs quantum well grown along [001] direction. If there is a one-monolayer fluctuation in the well size, how much will the effective bandgap change? This example gives an idea of how stringent the control has to be in order to exploit heterostructures.What is a matrix used in cyclic voltammetry? Define and give example of suchLinear density is a measure of how much a crystallographic vector is occupied by atoms, and is calculated as as the length of the atoms on the vector over the length of the vector. Calculate the following linear densites for the [100] and [110] vectors for:a. an FCC crystalb. a BCC crystal KINDLY ANSWER PLS NEEDED ASAP
- What point defects are possible for Al2O3 as an impurity in MgO? How many Al3+ ions must be added to form each of these defects? Explain.Spacing between the (200) planes is twice as big as the spacing between the 100 planes in BCC unit cells. True or false.A coherently strained quantum well laser has to be made from InxGa1-xAs on a GaAs substrate. If the minimum thickness of the region is 50 Ǻ, calculate the maximum composition of In that can be tolerated. Assume that the lattice constant of the alloy can be linearly interpolated from its components.
- What are the main advantages and limitations of the Valencia Linkage Theory?atomic radius is 0.1430 nm calculate the planer density of (211) plane at BCC structureSketch portions of a linear polypropylene molecule that are (a) syndiotactic, (b)atactic, and (c) isotactic. Use two-dimensional schematics.
- how the liquid junction potential can be eliminated ?Fluorite (CaF2) has a face centered cubic structure, space group 225, with network parameter equal to 5.45 Å), with four CaF2 units per cell unitary (Ca+ at site 4a(0,0,0) and F- at site 8c(1/4.1/4.1/4 and 3/4.3/4.3/4) + face centered cubic lattice translations for both ions). a) Get a simplified expression for the structure factor F(hkl) of fluorite. (b) What condition must be fulfilled by the Miller indices h,k,l in such a way that F(hkl) ≠ 0?9) A Cu monocrystal (FCC) of 10 cm length is pulled in tension. The stress axis is [¯123].a) Which is the stress system with the highest resolved shear stress?(b) If the extension of the crystal continues until a second slip systembecomes operational, what will this system be?(c) What rotation will be required to activate the second system?(d) How much longitudinal strain is required to activate the second system?