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- One litre of a saturated aqueous solution of Ag2SO4 (MW = 311.79 g mol- 1) at 25 °C is evaporated to dryness. 4.844 g of Ag2SO4 residue was produced. What is the solubility product (Ksp)?An acid solution containing 2 per cent by mass of NaNO3, and an unknown concentration of HNO3 is used to regenerate a strong acid resin. After sufficient acid had been passed over the resin for equilibrium to attained, analysis showed that 10 per cent of resin sites were occupied by sodium ions. What was the concentration of HNO3 in the solution, if its density were 1,030 kg/cu.m.?What wt of magnetite should be taken for analysis in order that after converting to a precipitate of Fe2O3.xH2O, the percentage of Fe3O4 in the sample can be found by multiplying the wt in grams of the ignited precipitate (Fe2O3) by 100.
- In gravimetric analysis, co-precipitation occurs alongside with analyte precipitation,resulting in the introduction of impurity and excess mass. Occlusion and inclusion areamong the sources of impurities. Distinguish the difference between occlusion andinclusion and compare them using diagramsHexanoic acid was added to an immiscible biphasic solvent system, water and CCl4 at 20.0OC and the equilibrium concentrations of hexanoic acid were determined to be 3.66 g/L in H2O and 67.0 g/L in CCl4. Caluclate the distrubution coeffiecent (D2) of hexanoic acid in water with respect to CCl4.Suppose you have a soil that is made up of 10% organic matter with CEC = 200 cmol/kg, 40% kaolinitewith CEC = 10 cmol/kg, and 50% vermiculite with CEC = 100 cmol/kg.1- Calculate the overall CEC of the soil by taking a weighted average of the three soil components.2- What percentage of the overall CEC is contributed by the organic matter? How does that numbercompare to the 10% of the soil itself that is organic?
- Calculate the gravimetric factor of the following. 2 Fe is sought(Analyte), 1Fe2O3 is weighed (Precipitate)A sample of an iron ore was prepared for Fe3+ analysis as following: 3.4g of the sample was added anddissolved in acid environment then diluted to 250 mL using volumetric flask. After that, 10 mL of the resultingsolution was transferred by pipet to a 50-mL volumetric flask and continue to be diluted. The scientists foundout that this solution gives the concentration of Fe3+ as 2.3 mg/L. Find the weight percentage of Fe3+ in theoriginal sample.The Ksp values of two solid carbonates, A2CO3 and BCO3, were determined by preparing 250.0-mL saturated aqueous solutions of both solids and then determining the concentration of carbonate by titrating it with 0.01023 M HCl up to methyl orange endpoint. Solutions of A2CO3 and BCO3 required 6.184 mL and 3.456 mL of the titrant, respectively. a. What are the concentration of carbonate in each of the saturated solutions of A2CO3and BCO3?b. What are the Ksp values of A2CO3 and BCO3? c. If 8.721 mg A2CO3 and 1.769 mg BCO3 were needed to prepare the saturated solutions, what are the identity of A2CO3and BCO3 ?Hint: deduct the molecular weight of carbonated. Instead of distilled water, 250.0 mL of 0.10 M ANO3 was used to prepare a saturatedsolution of A2CO3 while 250.0 mL of 0.10 M B(NO3)2 was used for BCO3. Which will have a higher solubility?
- Potassium dichromate has several industrial applications. To determine the purity of the salt that will be used in different industrial processes, a sample mass equal to 2.660 g was dissolved and quantitatively transferred to a 500.00 mL flask. An aliquot of 25.00 mL of this solution was treated with excess KI and the released iodine was titrated with 0.1000 mol L-1 sodium thiosulfate, spending 27.00 mL. Calculate the purity of the analyzed salt. Data:K = 39.10 O = 16.00 Cr = 52.00 I = 126.9 S = 32.07Six iron tablets containing FeSO4.7H2O were dissolved in 100-ml of 0.1M HNO3 with gentle heating. All of the Fe2+ is converted to Fe3+ by the strong oxidizing conditions. After the solution had cooled to room temperature , 2.5-ml of 35wt% NH4OH was added. The precipitate Fe2O3-xH2O that was filtered weighed 0.345g. Thermogravimetric analysis of the crude product showed a 10.5% weight loss . A. How many waters of hydration were in the precipitate B. How much iron is present in each tabletA sample of feldspar weighing 1.500g is decomposed, and eventually there is obtained a mixture of KCl and NaCl weighing 0.1801 g. These chlorides are dissolved in H2O, a 50-mL pipetful of 0.08333 N AGNO3 is added, and the precipitate is filtered off. The filtrate requires 16.47 mL of 0.1000N KCNS, with ferric alum as indicator. Calculate the percentage of K2O in the silicate.