Q4: In the calcium fluorite. CaF2 structure, atoms occupy the position of % % %, which is not filled in the so-called zinc blende (ZnS) structure. That is, Ca occupies the positions of 000; 2 ½ 0; 0 ½ ½; ½ 0 , and F occupies the positions of 4 ¼% % ; % % % ; % % % ; % % % ; % % %; % % %; % % %; ¼¾ ¼ . Obtain the structure factor Fhki of CaF2 and also express it using the structure factor F (fcc) of a face-centered cubic lattice.

Chemistry & Chemical Reactivity
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter23: Carbon: Not Just Another Element
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Q4: In the calcium fluorite. CaF2 structure, atoms occupy the position of % % %,
which is not filled in the so-called zinc blende (ZnS) structure. That is, Ca occupies
the positions of 000; 2 ½ 0; 0 ½ ½; ½ 0 , and F occupies the positions of 4 ¼% % ;
% % % ; % % % ; % % % ; % %%; % % %; % % %; ¼ ¾ ¼ . Obtain the structure factor
Fhki of CaF2 and also express it using the structure factor F (fcc) of a face-centered
cubic lattice.
Transcribed Image Text:Q4: In the calcium fluorite. CaF2 structure, atoms occupy the position of % % %, which is not filled in the so-called zinc blende (ZnS) structure. That is, Ca occupies the positions of 000; 2 ½ 0; 0 ½ ½; ½ 0 , and F occupies the positions of 4 ¼% % ; % % % ; % % % ; % % % ; % %%; % % %; % % %; ¼ ¾ ¼ . Obtain the structure factor Fhki of CaF2 and also express it using the structure factor F (fcc) of a face-centered cubic lattice.
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