QI: Starting from toluene as the onlyorganic reagent you have and use anyother inorganic reagents to prepare:ҫн,BrBrQII: Starting from toluene as the onlyorganic reagent you have and use anyother inorganic reagents to prepare:ОНCH3Н,СCH3QIII: Starting from ethanol as the onlyorganic reagent you have and use anyother inorganic reagents to prepare:QIV: Starting from Benzene as the onlyorganic reagent you have and use anyother inorganic reagents to prepare:NH, QV: Starting from Cyclohexanol as theonly organic reagent you have and use anyother inorganic reagents to prepare:'N'QVI: Starting from benzene as the onlyorganic reagent you have and use anyother inorganic reagents to prepare:F.QVII: Starting from benzene as the onlyorganic reagent you have and use anyother inorganic reagents to prepare:

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Answered: QI: Starting from toluene as the only…

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter23: Amines

Section: Chapter Questions

Problem 23.67P

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Draw the organic products formed when cyclopentene is treated with each reagent. With some reagents, no reactionoccurs.a. H2 + Pd-Cb. H2 + Lindlar catalystc. Na, NH3d. CH3CO3He. [1] CH3CO3H; [2] H2O, HO–f. [1] OsO4 + NMO; [2] NaHSO3, H2Og. KMnO4, H2O, HO–h. [1] LiAlH4; [2] H2Oi. [1] O3; [2] CH3SCH3j. (CH3)3COOH, Ti[OCH(CH3)2]4, (–)-DETk. mCPBAl. Product in (k); then [1] LiAlH4; [2] H2O
Compund ( A) C6H12 is treated with chlorine in the presence of carbon tetrachloride to given (B)C6H12Cl2.Compund (B) is treated with alcoholic KoH,followed by NaNH2 ,resulting in this formation of (C).compound (C) is treated with hydrogen in the presence of nickel catalysts to give 2methylpentane. Compound (C) does not react with sodamide or ammonical solution of silver nitrate .Ozonolysis of (A) give two aldehyde, (D) and (E) .Compound (E) is identified as acetaldehyde .From this information,describe the structural formula (A) ,(B) ,(C) And (C).write equation for all reaction
Several sulfonylureas, a class of compounds containing RSO2NHCONHR, are useful drugs as orally active replacements for injected insulin in patients with adult-onset diabetes. These drugs decrease blood glucose concentrations by stimulating b cells of the pancreas to release insulin and by increasing the sensitivity of insulin receptors in peripheral tissues to insulin stimulation. Tolbutamide is synthesized by the reaction of the sodium salt of p-toluenesulfonamide and ethyl N-butylcarbamate . Propose a mechanism for this step.
Write out all the isomers of the compound with molecular formula C4H10O Select the normal/ primaryisomer and treat it with conc. H2SO4 and heat. Identify the reaction and give the product ‘A’ from it. Treatment of ‘A’ with HCl/H2O gives ‘B’ Treatment of ‘A’ with cold KMnO4/ -OH gives ‘C’ Treatment of ‘A’ with Hot KMnO4/-OH gives ‘D’ followed by acidification of the mixture to give ‘E’
Draw the structures, and show steriochemistry when applicable 1.(S)-3-bromoheptanal 2. Cis-3-phenylcyclopentanol 3. (s)-3-methyl-4-heptanone
Compound A of molecular formula C8H14 is reduced by sodium in liquid ammonia to give compound B of molecular formula C8H16. product (Y).Both A and B undergo hydrogenation in the presence of a platinum catalyst to give 2,5-dimethylhexane. Ozonolysis of B with an oxidative workup produces a carboxylic acid of molecular formula C4H8O2. Reaction of B with a peroxyacid gives a chiral C8H14O product, but reaction with bromine gives an achiral C8H14Br2 product. What are the identities of A and B?
An unknown alcohol with a molecular formula of C7H14O was oxidized to an aldehyde with HOCl. When an acidic solution of the alcohol was distilled, two alkenes were obtained. The alkene formed in greater yield was determined to be 1-methylcyclohexene. The other alkene formed the original un-known alcohol when treated with BH3/THF followed by H2O2, HO-, and H2O. Identify the unknown alcohol.
(Z)-9-Tricosene [(Z)-CH3(CH2)7CH CH(CH2)12CH3] is the sex pheromone of the female housefly. Synthetic (Z)-9-tricosene is used as bait to lure male flies to traps that contain insecticide. Using acetylene and alcohols of your choice as starting materials, along with any necessary inorganic reagents, show how you could prepare (Z)-9-tricosene.
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(10pts) Compound A, C10H16, was found to be optically active. On catalytic reduction over a palladium catalyst, 2 equivalents of hydrogen were absorbed, yielding compound B, CioH2o. On ozonolysis of A, two fragments were obtained. One fragment was identified as acetic acid (CHCOOH). The other fragment, compound C, was an optically active carboxylic acid, C8H14O2. Write reactions, and draw the correct structures for A-C, explain your answer in detail.
Choose from the options A-E and explain briefly by illustrations the chemistry behind each answer. Preamble: A reaction flask contains a 2-bromopentane in an ethanolic solution of sodium ethoxide at room temperature and results in the formation of two olefinic products. 1.Predict the products that would be formed from such a reaction A.1-pentene (80%) and 2-pentene (20%)B.1-pentene (20%) and 2-pentene (80 %)C.1-pentene (50 %) and 2-pentene (50 %)D.1-pentene (0 %) and 2-pentene (100 %)E.1-pentene (100 %) and 2-pentene (0 %) 2.What reaction pathway is followed by the reaction above?A.E2 dehydrohalogenation B.E1 dehydrohalogenationC.SN1 dehydrohalogenationD.SN2 dehydrohalogenationE.A mixture of E1 and E2 pathways 3.What is responsible for the formation of different products (major and minor).A.The different activated complex involved in the mechanism.B.Bimolecular Nucleophilic substitution reaction C.Bimolecular Elimination reaction D.The presence of sodium ethoxideE.The hybridisation…

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