Question 1: draw the curved arrow mechanism for the diels alder cycloadditions shown below (step 1). explain the diastereoselectivith observed in each case based on the endo transition states. Question 1: Draw the curved arrow mechanism for the Diels-Alder cycloadditions shown below(step 1). These reactions are catalyzed by a Lewis acid which enable the cycloadditions to takeplace at relatively low temperature for a better stereocontrol. Explain the diastereoselectivityobserved in each case based on the endo transition states.Question 2: For the synthesis of georgywood, provide the intermediates and product A after twosteps. (from Chapter 13)Examples of endo-Diels-Alder cycloadditionsCHOEYCHOteLewis acidstep 1усноLewis acidstep 1Xs²****Georgywood 15 pg/literfirst step towardsE Super Plus(R)rosteps 2-3MeAlCl₂step 4******AH2. MeMgBr3. swern oxidation

According to Alder's endo rule, groups present in outside at diene, groups present in endo at…

Answered: Question 1: draw the curved arrow…

Question 1: draw the curved arrow mechanism for the diels alder cycloadditions shown below (step 1). explain the diastereoselectivith observed in each case based on the endo transition states.

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter8: Addition Via Carbocation

Section: Chapter Questions

Problem 9E

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Question 1: draw the curved arrow mechanism for the diels alder cycloadditions shown below (step 1). explain the diastereoselectivith observed in each case based on the endo transition states.

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Step 1: Define the rule of stereochemistry of Diels-Alder Reaction

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Step 2: Draw the mechanism and transition state of reaction- 1

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Step 3: Draw the mechanism and transition state and mechanism for the reaction 2

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